Skip to main content
Log in

Structure of polyoxypropylene polyols synthesized with basic and dimetal cyanide catalytic systems according to 13C NMR spectroscopic data

  • Catalysis
  • Published:
Russian Journal of Applied Chemistry Aims and scope Submit manuscript

Abstract

13C NMR spectroscopy was used to make a comparative characterization of the distribution of polyoxypropylene polyols synthesized on basic (KOH) and dimetal cyanide catalysts over the type of functionality, regioregularity, and stereotacticity.

This is a preview of subscription content, log in via an institution to check access.

Access this article

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Similar content being viewed by others

References

  1. Gagnon, S.D., Encyclopedia of Polymer Science and Technology, John Wiley & Sons, Inc., 2008, pp. 1–38.

  2. Entelis, S.G., Evreinov, V.V., and Kuzaev, A.I., Reaktsionnosposobnye oligomery (Reactive Oligomers), Moscow: Khimiya, 1985.

    Google Scholar 

  3. Kim, I., Ahn, J.-T., Ha, Ch.S., et al., Polymer, 2003, vol. 44, no. 11, pp. 3417–3428.

    Article  CAS  Google Scholar 

  4. Jacquier-Gonod, V., Llauro, M.-Fr., and Hamaide, Th., Macromol. Chem. Phys., 2000, vol. 201, no. 1, pp. 12–20.

    Article  CAS  Google Scholar 

  5. Chisholm, M.H. and Navarro-Llobet, D., Macromolecules, 2002, vol. 35, no. 6, pp. 2389–2392.

    Article  CAS  Google Scholar 

  6. De Lucas, A., Rodriguez, L., Perez-Collado, M., et al., Polym. Internat., 2002, vol. 51, no. 10, pp. 1041–1046.

    Article  Google Scholar 

  7. Chen, S. and Chen, L., Coll. Polym. Sci., 2003, vol. 281, no. 3, pp. 288–291.

    Article  CAS  Google Scholar 

  8. Rexin, O. and Muelhaupt, R., Macromol. Chem. Phys., 2003, vol. 204, no. 8, pp. 1102–1109.

    Article  CAS  Google Scholar 

  9. Chen, S., Xu, N., and Shi, J., Progr. Org. Coat., 2004, vol. 49, no. 2, pp. 125–129.

    Article  CAS  Google Scholar 

  10. Byun, S.H., Seo, H.S., Lee, S.H., et al., Macromol. Res., 2007, vol. 15, no. 5, pp. 393–395.

    Article  CAS  Google Scholar 

  11. Lee, S.H., Lee, I.K., Ha, J.Y., et al., Ind. Eng. Chem. Res., 2010, vol. 49, no. 9, pp. 4107–4116.

    Article  CAS  Google Scholar 

  12. Šutinská V., Pajtášova M., Ondrušová D., et al., J. Therm. Anal. Calorim., 2011, vol. 104, no. 6, pp. 923–927.

    Article  Google Scholar 

  13. Saito, T., Nakaie, S., Kinoshita, M., et al., Metrologia, 2004, vol. 41, no. 3, pp. 213–218.

    Article  CAS  Google Scholar 

  14. Alvarado, E., Practical Guide for Quantitative 1D NMR Integration, University of Michigan, 2010. http://www.umich.edu/~chemnmr/docs/Quantitative-NMR.pdf.

  15. Schilling, F.C. and Tonelli, A.E., Macromolecules, 1986, vol. 19, no. 5, pp. 1337–1343.

    Article  CAS  Google Scholar 

  16. Heatley, F., Luo, Y.-Zh., Ding, J.-F., et al., Macromolecules, 1988, vol. 21, no. 9, pp. 2713–2721.

    Article  CAS  Google Scholar 

  17. Miura, K., Kitayama, T., Hatada, K., et al., Polymer J., 1993, vol. 25, no. 7, pp. 697–705.

    Article  CAS  Google Scholar 

  18. Yu, G.-E., Masters, A.J., Heatley, F., et al., Macromol. Chem. Phys., 1994, vol. 195, no. 5, pp. 1517–1538.

    Article  CAS  Google Scholar 

  19. Carr, R.H., Hernalsteen, J., and Devos, J., J. Appl. Polym. Sci., 1994, vol. 52, no. 8, pp. 1015–1022.

    Article  CAS  Google Scholar 

  20. Yang, L., Heatley, F., Blease, T.G., et al., Eur. Polym. J., 1996, vol. 32, no. 5, pp. 535–547.

    Article  CAS  Google Scholar 

  21. Sasanuma, Y., Iwata, T., Kato, Y., et al., J. Phys. Chem., 2001, vol. 105, no. 13, pp. 3277–3283.

    Article  CAS  Google Scholar 

  22. Makhiyanov, N. and Safin, D.Kh., Vysokomol. Soedin., Ser. B, 2006, vol. 48, no. 2, pp. 359–369.

    CAS  Google Scholar 

  23. Makhiyanov, N., Safin, D.Kh., and Khachaturov, A.S., Zh. Prikl. Khim., 2010, vol. 83, no. 6, pp. 983–989.

    Google Scholar 

  24. Vakhtina, I.A., Petrakova, E.A., Pentsel’, U., et al., Vysokomol. Soedin., Ser. A, 1980, vol. 22, no. 7, pp. 1671–1674.

    CAS  Google Scholar 

  25. Knopp, H., Gladkovskii, G.A., Petrakova, U.F., et al., Vysokomol. Soedin., Ser. A, 1980, vol. 22, no. 8, pp. 1788–1794.

    CAS  Google Scholar 

Download references

Author information

Authors and Affiliations

Authors

Corresponding author

Correspondence to N. Makhiyanov.

Additional information

Original Russian Text © N. Makhiyanov, D.Kh. Safin, R.R. Sharifullin, A.S. Biktimerova, 2012, published in Zhurnal Prikladnoi Khimii, 2012, Vol. 85, No. 12, pp. 1991–1998.

Rights and permissions

Reprints and permissions

About this article

Cite this article

Makhiyanov, N., Safin, D.K., Sharifullin, R.R. et al. Structure of polyoxypropylene polyols synthesized with basic and dimetal cyanide catalytic systems according to 13C NMR spectroscopic data. Russ J Appl Chem 85, 1879–1886 (2012). https://doi.org/10.1134/S1070427212120142

Download citation

  • Received:

  • Published:

  • Issue Date:

  • DOI: https://doi.org/10.1134/S1070427212120142

Keywords

Navigation