Abstract
13C NMR spectroscopy was used to make a comparative characterization of the distribution of polyoxypropylene polyols synthesized on basic (KOH) and dimetal cyanide catalysts over the type of functionality, regioregularity, and stereotacticity.
Similar content being viewed by others
References
Gagnon, S.D., Encyclopedia of Polymer Science and Technology, John Wiley & Sons, Inc., 2008, pp. 1–38.
Entelis, S.G., Evreinov, V.V., and Kuzaev, A.I., Reaktsionnosposobnye oligomery (Reactive Oligomers), Moscow: Khimiya, 1985.
Kim, I., Ahn, J.-T., Ha, Ch.S., et al., Polymer, 2003, vol. 44, no. 11, pp. 3417–3428.
Jacquier-Gonod, V., Llauro, M.-Fr., and Hamaide, Th., Macromol. Chem. Phys., 2000, vol. 201, no. 1, pp. 12–20.
Chisholm, M.H. and Navarro-Llobet, D., Macromolecules, 2002, vol. 35, no. 6, pp. 2389–2392.
De Lucas, A., Rodriguez, L., Perez-Collado, M., et al., Polym. Internat., 2002, vol. 51, no. 10, pp. 1041–1046.
Chen, S. and Chen, L., Coll. Polym. Sci., 2003, vol. 281, no. 3, pp. 288–291.
Rexin, O. and Muelhaupt, R., Macromol. Chem. Phys., 2003, vol. 204, no. 8, pp. 1102–1109.
Chen, S., Xu, N., and Shi, J., Progr. Org. Coat., 2004, vol. 49, no. 2, pp. 125–129.
Byun, S.H., Seo, H.S., Lee, S.H., et al., Macromol. Res., 2007, vol. 15, no. 5, pp. 393–395.
Lee, S.H., Lee, I.K., Ha, J.Y., et al., Ind. Eng. Chem. Res., 2010, vol. 49, no. 9, pp. 4107–4116.
Šutinská V., Pajtášova M., Ondrušová D., et al., J. Therm. Anal. Calorim., 2011, vol. 104, no. 6, pp. 923–927.
Saito, T., Nakaie, S., Kinoshita, M., et al., Metrologia, 2004, vol. 41, no. 3, pp. 213–218.
Alvarado, E., Practical Guide for Quantitative 1D NMR Integration, University of Michigan, 2010. http://www.umich.edu/~chemnmr/docs/Quantitative-NMR.pdf.
Schilling, F.C. and Tonelli, A.E., Macromolecules, 1986, vol. 19, no. 5, pp. 1337–1343.
Heatley, F., Luo, Y.-Zh., Ding, J.-F., et al., Macromolecules, 1988, vol. 21, no. 9, pp. 2713–2721.
Miura, K., Kitayama, T., Hatada, K., et al., Polymer J., 1993, vol. 25, no. 7, pp. 697–705.
Yu, G.-E., Masters, A.J., Heatley, F., et al., Macromol. Chem. Phys., 1994, vol. 195, no. 5, pp. 1517–1538.
Carr, R.H., Hernalsteen, J., and Devos, J., J. Appl. Polym. Sci., 1994, vol. 52, no. 8, pp. 1015–1022.
Yang, L., Heatley, F., Blease, T.G., et al., Eur. Polym. J., 1996, vol. 32, no. 5, pp. 535–547.
Sasanuma, Y., Iwata, T., Kato, Y., et al., J. Phys. Chem., 2001, vol. 105, no. 13, pp. 3277–3283.
Makhiyanov, N. and Safin, D.Kh., Vysokomol. Soedin., Ser. B, 2006, vol. 48, no. 2, pp. 359–369.
Makhiyanov, N., Safin, D.Kh., and Khachaturov, A.S., Zh. Prikl. Khim., 2010, vol. 83, no. 6, pp. 983–989.
Vakhtina, I.A., Petrakova, E.A., Pentsel’, U., et al., Vysokomol. Soedin., Ser. A, 1980, vol. 22, no. 7, pp. 1671–1674.
Knopp, H., Gladkovskii, G.A., Petrakova, U.F., et al., Vysokomol. Soedin., Ser. A, 1980, vol. 22, no. 8, pp. 1788–1794.
Author information
Authors and Affiliations
Corresponding author
Additional information
Original Russian Text © N. Makhiyanov, D.Kh. Safin, R.R. Sharifullin, A.S. Biktimerova, 2012, published in Zhurnal Prikladnoi Khimii, 2012, Vol. 85, No. 12, pp. 1991–1998.
Rights and permissions
About this article
Cite this article
Makhiyanov, N., Safin, D.K., Sharifullin, R.R. et al. Structure of polyoxypropylene polyols synthesized with basic and dimetal cyanide catalytic systems according to 13C NMR spectroscopic data. Russ J Appl Chem 85, 1879–1886 (2012). https://doi.org/10.1134/S1070427212120142
Received:
Published:
Issue Date:
DOI: https://doi.org/10.1134/S1070427212120142