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Palladium catalysts on porous nickel substrates for alcohol fuel cells

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Abstract

Parameters characterizing the active surface of catalytic palladium layers formed from mixed glycinate-chloride and ammonia complexes of palladium(II) were determined. Cyclic voltammetry on a rotating disc electrode was used to study the catalytic activity of nickel substrates and palladium layers in the reaction of methanol and ethanol oxidation in an alkaline medium. It was shown that electrodes with palladium deposited from mixed glycinate-chloride solutions have a higher catalytic activity that those formed from ammonia palladium(II) complexes.

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Authors and Affiliations

  1. St. Petersburg State University, St. Petersburg, Russia

    T. G. Nikiforova, O. A. Datskevich & V. V. Maleev

Authors
  1. T. G. Nikiforova
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  2. O. A. Datskevich
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  3. V. V. Maleev
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Correspondence to T. G. Nikiforova.

Additional information

Original Russian Text © T.G. Nikiforova, O.A. Datskevich, V.V. Maleev, 2012, published in Zhurnal Prikladnoi Khimii, 2012, Vol. 85, No. 12, pp. 1983–1990.

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Nikiforova, T.G., Datskevich, O.A. & Maleev, V.V. Palladium catalysts on porous nickel substrates for alcohol fuel cells. Russ J Appl Chem 85, 1871–1878 (2012). https://doi.org/10.1134/S1070427212120130

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  • DOI: https://doi.org/10.1134/S1070427212120130

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