Abstract
The kinetic features were examined for transesterifi cation of methyl acrylate with N,N-dimethylethanolamine in the presence of tetra(N,N-dimethylaminoethyl) titanate at different molar ratios of the reactants and at temperatures within 50–80°C, as well as for side reactions of Michael addition at 95–125°C. The major parameters governing the selectivity of the synthesis of N,N-dimethylaminoethyl acrylate were determined.
This is a preview of subscription content, log in via an institution to check access.
Similar content being viewed by others
References
EP Patent 0906902.
US Patent 6977310.
US Patent 7078560.
Jiang, P., Zhang, D., Li, Q., and Lu, Y., Catal. Lett., 2006, vol. 110, nos. 1–2, pp. 101–106.
US Patent Application 2009/0253930 A1.
US Patent Application 2004/0171868 A1.
Rehberg, C.E., Dixon, M.B., and Fisher, C.H., J. Am. Chem. Soc., 1947, vol. 69, no. 12, pp. 2966–2970.
Marsi, M., Inorg. Chem., 1988, vol. 27, no. 18, pp. 3062–3064.
Bharara, P.C., Gupta, V.D., and Mehrotra, R.C., Z. Anorg. Allg. Chem., 1974, vol. 403, no. 3, pp. 337–346.
Rowell, P. P. and Chiou, C.Y., J. Med. Chem., 1976, vol. 19, no. 2, pp. 300–303.
Kumbhar, A.G., Narasimhan, S.V., and Mathur, P.K., Anal. Chim. Acta, 1994, vol. 294, pp. 103–111.
Author information
Authors and Affiliations
Corresponding author
Additional information
Original Russian Text ©P.A. Demidov, I.A. Lavrent’ev, V.V. Potekhin, 2012, published in Zhurnal Prikladnoi Khimii, 2012, Vol. 85, No. 11, pp. 1766–1770.
Rights and permissions
About this article
Cite this article
Demidov, P.A., Lavrent’ev, I.A. & Potekhin, V.V. Reaction of methyl acrylate with N,N-dimethylethanolamine in the presence of a titanium alkoxide. Russ J Appl Chem 85, 1676–1680 (2012). https://doi.org/10.1134/S1070427212110079
Received:
Published:
Issue Date:
DOI: https://doi.org/10.1134/S1070427212110079