Abstract
Potentio- and conductometric titration was used to study the interaction in sulfur(IV) oxide-ethanolamines-water systems in comparison with the previously obtained pH-metric data on how the corresponding onium sulfites, hydrosulfites, and pyrosulfites are formed. The ionic and molecular compositions of these solutions were calculated. Correlations between the characteristics of pH-metric titration curves of aqueous solutions of ethanolamines with sulfur(IV) oxide and the relative stability of onium sulfates were revealed.
Similar content being viewed by others
References
Ennan, A.A., Coordination Compounds of Silicon Tetrafluoride and Hydrofluorides of Nitrogen-containing Bases, Doctoral (Chem.) Sci. Dissertation, Odessa, 1975.
US Patent 3904735.
US Patent 4363791.
Khoma, R.E., Nikitin, V.I., and Gavrilenko, M.I., Vestn. Odessa Nats. Univ., Khim., 2000, vol. 5, no. 5, pp. 39–44.
Yavors’kii, V.T., Savchuk, L.V., Bert, E.S., and Olenich, R.R., Sbornik nauchnykh trudov Mezhdunarodnoi nauchno-tekhnicheskoi konferentsii “Sovremennye problemy khimicheskoi tekhnologii neorganicheskikh veshchestv” (Coll. of Sci. Works of Int. Sci.-Techn. Conf. “Modern Problems of Chemical Technology of Inorganic Substances”), Odessa, 2001, vol. 2, pp. 312–315.
Khoma, R.E., Shestaka, A.A., and Gel’mbol’dt, V.O., Vopr. Khim. Khim. Tekhnol., 2009, no. 5, pp. 86–89.
Khoma, R.E., Shestaka, O.O., and Gel’mbol’dt, V.O., Vestn. Odessa Nats. Univ., Khim., 2010, vol. 15, no. 12, pp. 34–44.
Khoma, R.E. and Gavrilenko, M.I., Zh. Obshch. Khim., 2010, vol. 80, no. 5, pp. 729–734.
Khoma, R.E., Shestaka, A.A., Sokhranenko, G.P., et al., Zh. Prikl. Khim., 2011, vol. 84, no. 1, pp. 18–24.
Khoma, R.E., Gavrilenko, M.I., and Nikitin, V.I., Zh. Obshch. Khim., 2005, vol. 75, no. 5, pp. 771–777.
Kel’man, I.N., Brutskus, E.B, and Osherovich, R.Kh., Metody analiza pri kontrole proizvodstva sernoi kisloty i fosfornykh udobrenii (Analytical Methods for Monitoring of Manufacture of Sulfuric Acid and Phosphate Fertilizers), Moscow: Khimiya, 1965.
Klimova, V.A., Osnovnye metody analiza organicheskikh soedinenii (Basic Methods for Analysis of Organic Compounds), Moscow: Khimiya, 1975.
Horner, D.A. and Connick, R.E., Inorg. Chem., 1986, vol. 25, no. 14, pp. 2414–2417.
Romanenko, S.A., Component Composition of Aqueous Solutions of Sulfur(IV) Oxide, Cand. Sci. Disseration, Leningrad, 1986.
Baggio, S., Acta Crystal., Section B: Struct. Crystallogr. Crystal Chem., 1971, vol. B27, no. 3, pp. 517–522.
Wiberg, E., Wiberg, N., and Holleman, A.F., Inorganic Chemistry, Berlin, 2001, pp. 540–541.
Cotton, F.A., Wilkinson, G.M., Carlos, A., and Bochmann, M., Advanced Inorganic Chemistry, John Wiley & Sons, 1999.
Travina, O.A., Kozlov, Yu.N., Purmal’, A.P., and Travin, S.O., Kinet. Kataliz, 1997, vol. 38, no. 2, pp. 242–246.
Ermakov, A.N., Poskrebyshev, G.A., and Purmal’, A.P., Kinet. Kataliz, 1997, vol. 38, no. 3, pp. 325–338.
Khudyakova, T.A. and Kreshkov, A.P., Konduktometricheskii metod analiza (Conductometric Analysis), Moscow: Vysshaya Shkola, 1975.
Hartley, F.R., Burges, C., and Alcock, R.M., Solution Equilibria, New York: Ellis Horwood, 1980.
Author information
Authors and Affiliations
Corresponding author
Additional information
Original Russian Text © R.E. Khoma, A.A. Shestaka, V.O. Gel’mbol’dt, 2012, published in Zhurnal Prikladnoi Khimii, 2012, Vol. 85, No. 11, pp. 1656–1665.
Rights and permissions
About this article
Cite this article
Khoma, R.E., Shestaka, A.A. & Gel’mbol’dt, V.O. On interaction of sulfur(IV) oxide with aqueous solutions of ethanolamines. Russ J Appl Chem 85, 1667–1675 (2012). https://doi.org/10.1134/S1070427212110067
Received:
Published:
Issue Date:
DOI: https://doi.org/10.1134/S1070427212110067