Russian Journal of Applied Chemistry

, Volume 85, Issue 9, pp 1355–1365 | Cite as

Gas-chromatographic identification of products formed in iodination of methyl phenols by retention indices

  • I. V. GruzdevEmail author
  • I. M. Kuzivanov
  • I. G. Zenkevich
  • B. M. Kondratenok
Sorption and Chromatography


Iodination reaction followed by conversion of iodine-substituted methylphenols to the corresponding trifl uoroacetates was suggested for improving the sensitivity of the gas-chromatographic determination of phenol and its methyl-substituted derivatives (al isomers of mono- and diethylphenols, 2,3,5-, 2,3,6-, and 3,4,5-trimethylphenols) in aqueous media. Acylation products of iodo methylphenols (104 compounds) were identified by linear-logarithmic retention indices on a standard nonpolar polydimethylsiloxane stationary phase, and the pattern of their variation with the number and nature of substituents were characterized. A procedure for identification of methyl-substituted phenols in water in their gas-chromatographic determination with an electron-capture detector was developed.


Retention Index Methylphenol Ortho Position Iodine Atom Dimethylphenol 
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Copyright information

© Pleiades Publishing, Ltd. 2012

Authors and Affiliations

  • I. V. Gruzdev
    • 1
    Email author
  • I. M. Kuzivanov
    • 2
  • I. G. Zenkevich
    • 3
  • B. M. Kondratenok
    • 1
  1. 1.Institute of Biology, Komi Scientific Center, Ural BranchRussian Academy of SciencesSyktyvkar, Komi RepublicRussia
  2. 2.Syktyvkar State UniversitySyktyvkar, Komi RepublicRussia
  3. 3.St. Petersburg State UniversitySt. PetersburgRussia

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