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Effect of nickel oxide additive on properties of catalysts used in the reaction of selective oxidation of carbon monoxide

  • Applied Electrochemistry and Corrosion Protection of Metals
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Abstract

Effect of nickel oxide additives on the oxidation selectivity of carbon monoxide in the presence of hydrogen was studied for the widely recognized system constituted by copper and cerium oxides. It was shown that a significant positive effect is observed upon introduction of the nickel-containing additive (≤0.3%) due to the electron-donor effect of nickel oxide. It was demonstrated that the catalyst of composition NiO/CuO/CeO2/Al2O3 shows high selectivity in the reaction of CO oxidation.

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Authors and Affiliations

  1. Baikov Institute of Metallurgy and Materials Science, Russian Academy of Sciences, Moscow, Russia

    L. V. Gorobinskii & G. Yu. Yurkov

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  1. L. V. Gorobinskii
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  2. G. Yu. Yurkov
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Correspondence to G. Yu. Yurkov.

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Original Russian Text © L.V. Gorobinskii, G.Yu. Yurkov, 2012, published in Zhurnal Prikladnoi Khimii, 2012, Vol. 85, No. 9, pp. 1429–1435.

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Gorobinskii, L.V., Yurkov, G.Y. Effect of nickel oxide additive on properties of catalysts used in the reaction of selective oxidation of carbon monoxide. Russ J Appl Chem 85, 1345–1350 (2012). https://doi.org/10.1134/S107042721209008X

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  • DOI: https://doi.org/10.1134/S107042721209008X

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