Abstract
Emulsifiers were prepared by base saponification of sunflower-seed oil production waste, soapstock. The rate of styrene polymerization in the presence of these surfactants and various amounts of an initiator (potassium persulfate) was estimated. The polystyrene yield and molecular weight were found. For six latexes synthesized, the colloid-chemical characteristics (dry residue, surface tension, electrokinetic potential, rapid coagulation threshold, latex globule size) were determined.
This is a preview of subscription content, access via your institution.
References
Arutyunyan, N.S., Laboratornyi praktikum po khimii zhirov (Practical Laboratory Course of Fat Chemistry), St. Petersburg: GIORD, 2004.
D’yakonova, L.M., Kauchuk Rezina, 2007, no. 3, pp. 14–17.
Arutyunyan, N.S., Rafinatsiya zhirov i masel: Teoreticheskie osnovy, praktika, tekhnologiya, oborudovanie (Refining of Fats and Oils: Theoretical Principles, Practice, Technology, Equipment), St. Petersburg: GIORD, 2004.
Valovotskaya, S.N., Smirnov, G.Ya., and Rafal’son, A.G., Maslozhir. Prom-st., 1989, no. 8, pp. 7–12.
Tyutyunnikov, B.N., Naumenko, P.V., Tovbin, I.M., et al., Tekhnologiya pererabotki zhirov (Fat Processing Technology), Moscow: Pishchevaya Prom-st., 1970.
Poyarkova, T.N., Kudrina, G.V., and Korystina, L.A., Zh. Prikl. Khim., 2011, no. 12, pp. 2038–2042.
Poyarkova, T.N., Nikulin, S.S., Pugacheva, I.N., et al., Praktikum po kolloidnoi khimii lateksov: Uchebnoe posobie (Practical Course of Colloidal Chemistry of Latexes: Textbook), Moscow: Akad. Estestvoznaniya, 2011.
Abramzon, A.A., Poverkhnostno-aktivnye veshchestva: Svoistva i primenenie (Surfactants: Properties and Use), Leningrad: Khimiya, 1981.
Shestakov, A.S., Vysokomolekulyarnye soedineniya: Praktikum (Macromolecular Compounds: Practical Course), Voronezh: Voronezhsk. Gos. Univ., 2004.
Rakhmatulina, A.P., Formulations Based on Oleochemical Surfactants in the Technology of Synthesis and Processing of Carbon-Chain Elastromers, Cand. Sci. Dissertation, Kazan, 2009.
Sieglaff, C.L. and Mazur, J., J. Colloid Sci., 1962, no. 10, p. 194.
Author information
Authors and Affiliations
Corresponding author
Additional information
Original Russian Text © T.N. Poyarkova, G.V. Kudrina, E.V. Sotnikova, Yu.I. Prokof’ev, 2012, published in Zhurnal Prikladnoi Khimii, 2012, Vol. 85, No. 8, pp. 1324–1329.
Rights and permissions
About this article
Cite this article
Poyarkova, T.N., Kudrina, G.V., Sotnikova, E.V. et al. Influence of soapstock preparation conditions and initiator amount on the colloid-chemical properties of polystyrene latex. Russ J Appl Chem 85, 1259–1263 (2012). https://doi.org/10.1134/S1070427212080204
Received:
Published:
Issue Date:
DOI: https://doi.org/10.1134/S1070427212080204
Keywords
- Styrene
- Sodium Silicate
- Potassium Persulfate
- Electrokinetic Potential
- Polystyrene Latex