Abstract
Experimental data were used to study the hydrolysis kinetics and construct an approximating expression for calculation of quasistationary hydrolysis constants for sodium borohydride in a wide range of alkali concentrations and temperatures.
Similar content being viewed by others
References
Wu, Y., Kelly, M.T., and Ortega, J.V., Review of Chemical Processes for the Synthesis of Sodium Borohydride, Millennium Cell Inc. Under DOE Cooperative Agreement DE-FC36-04GO14008, 2004.
US Patent 7214439.
US Patent 7019105.
US Patent 6706909.
Shabunya, S.I., Martynenko, V.V., Minkina, V.G., et al., Proc. Third Int. Workshop “Nonequilibrium Processes in Combustion and Plasma Based Technologies,” Minsk, 2008, pp. 125–130.
Nesteruk, A.A., Shabunya, S.I., Minkina, V.G., et al., Proc. Annual Conf. Young Scientists on Energy Issues “CYSENI 2009,” Kaunas: LEI, 2009, Electronic Resource.
Nesteruk, A.A., Shabunya, S.I., Minkina, V.G., et al., Inzh.-Fiz. Zh., 2011, vol. 84, no. 5, pp. 981–989.
Jensen, E.H., A Study on Sodium Borohydride, Copenhagen, 1954.
Mesmer, R.E. and Jolly, W.L., Inorg. Chem., 1962, vol. 1, no. 3, pp. 608–612.
Khain, V.S. and Volkov, A.A., Zh. Prikl. Khim., 1980, vol. 53, no. 11, pp. 2404–2407.
Mochalov, K.N., Shifrin, Kh.V., and Bogonostsev, A.S., Zh. Fiz. Khim., 1963, vol. 37, no. 11, pp. 2404–2407.
Mochalov, K.N., Shifrin, Kh.V., and Bogonostsev, A.S., Kinet. Kataliz, 1964, vol. 5, no. 1, pp. 174–177.
Mochalov, K.N., Khain, V.S., and Gil’manshin, G.G., Kinet. Kataliz, 1965, vol.6, no. 3, pp. 541–543.
Mochalov, K.N., Khain, V.S., and Gil’manshin, G.G., Doklady Akad. Nauk SSSR, 1965, vol. 162, no. 3, pp. 613–616.
Kreevoy, M.M. and Hutchins, J.E.C., J. Am. Chem. Soc., 1972, vol. 94, no. 18, pp. 6371–6376.
Kreevoy, M.M. and Jacobson, R.W., Ventron Alembic, 1979, vol. 15, pp. 2–3.
Prokopchik, A.Yu. and Shalkauskene, Yu.A., Zh. Fiz. Khim., 1970, vol. 44, p. 2941.
Author information
Authors and Affiliations
Corresponding author
Additional information
Original Russian Text © S.I. Shabunya, V.G. Minkina, A.A. Nesteruk, V.V. Martynenko, V.I. Kalinin, 2012, published in Zhurnal Prikladnoi Khimii, 2012, Vol. 85, No. 8, pp. 1225–1232.
Rights and permissions
About this article
Cite this article
Shabunya, S.I., Minkina, V.G., Nesteruk, A.A. et al. Experimental studies of the hydrolysis kinetics of aqueous-alkaline solutions of sodium borohydride. Russ J Appl Chem 85, 1167–1175 (2012). https://doi.org/10.1134/S1070427212080058
Received:
Published:
Issue Date:
DOI: https://doi.org/10.1134/S1070427212080058