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Reaction of products of thermal and thermal oxidative degradation of polyvinyl chloride with barium hydroxide

  • Macromolecular Compounds and Polymeric Materials
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Abstract

The reaction of products of thermal and thermal oxidative degradation of polyvinyl chloride with barium hydroxide was studied. The degree of binding of chlorine and carbon atoms from polyvinyl chloride in reactions of barium hydroxide with hydrogen chloride and carbon dioxide formed by degradation and oxidation of the polymer was studied in relation to the hydroxide/polymer weight ratio and temperature. The activation energies of the reaction and the specific rates of formation of barium chloride and carbonate were calculated.

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Authors and Affiliations

  1. Institute of Technical Chemistry, Ural Branch, Russian Academy of Sciences, Perm, Russia

    O. V. Rudometova, A. A. Fedorov & Yu. S. Chekryshkin

Authors
  1. O. V. Rudometova
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  2. A. A. Fedorov
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  3. Yu. S. Chekryshkin
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Corresponding author

Correspondence to A. A. Fedorov.

Additional information

Original Russian Text © O.V. Rudometova, A.A. Fedorov, Yu.S. Chekryshkin, 2012, published in Zhurnal Prikladnoi Khimii, 2012, Vol. 85, No. 4, pp. 655–658.

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Rudometova, O.V., Fedorov, A.A. & Chekryshkin, Y.S. Reaction of products of thermal and thermal oxidative degradation of polyvinyl chloride with barium hydroxide. Russ J Appl Chem 85, 670–673 (2012). https://doi.org/10.1134/S1070427212040234

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  • DOI: https://doi.org/10.1134/S1070427212040234

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