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Continuous synthesis of organomagnesium compounds

  • Organic Synthesis and Industrial Organic Chemistry
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Abstract

Continuous synthesis of organomagnesium compounds by the reaction of magnesium with haloalkanes RX (R = Et, n-Bu, n-Oct, c-Hex, Ph; X = Cl, Br) in a stirred column-type apparatus was studied. The effects of the solvent, solvating solvent to RX molar ratio, and temperature in the reaction zone on the RX conversion and yield of organomagnesium compounds was examined.

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Authors and Affiliations

  1. State Research Institute of Chemistry and Technology of Organoelement Compounds, State Scientific Center of the Russian Federation, Moscow, Russia

    A. A. Grachev, A. O. Klochkov & V. I. Shiryaev

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  1. A. A. Grachev
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  2. A. O. Klochkov
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  3. V. I. Shiryaev
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Correspondence to A. A. Grachev.

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Original Russian Text © A.A. Grachev, A.O. Klochkov, V.I. Shiryaev, 2012, published in Zhurnal Prikladnoi Khimii, 2012, Vol. 85, No. 4, pp. 613–622.

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Grachev, A.A., Klochkov, A.O. & Shiryaev, V.I. Continuous synthesis of organomagnesium compounds. Russ J Appl Chem 85, 629–638 (2012). https://doi.org/10.1134/S1070427212040167

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  • DOI: https://doi.org/10.1134/S1070427212040167

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