Abstract
The results of tests in fluoride-containing solutions were presented for an antimony electrode, solidstate polyvinyl chloride-graphite electrodes modified by a quinone-hydroquinone series system, and electrodes made of silicate glasses, in particular, of commercial formulations. A technique and criteria were proposed for comparison of the performance characteristics of different glass electrodes in fluoride-containing solutions, and samples most resistant to hydrofluoric acid were identified.
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References
Bates, R.G., Determination of pH: Theory and Practice, New York: Wiley, 1964.
Metrohm USA Inc. Combined Antimony Electrode; http://www.metrohmusa.com/Products/Titration/Electrodes/pHElectrodes/60421100.html.
Kazak, A.S., Rodionova, S.A., Trofimov, M.A., and Pendin, A.A., Zh. Anal. Khim., 1996, vol. 51, no. 9, pp. 970–974.
Han, Won-Sik, Park, Myon-Yong, Chung, Koo-Chun, et al., Electroanalysis, 2000, vol. 13,issue 11, pp. 955–959.
Lutov, V.M. and Mikhelson, K.N., Sens. Actuators, B: Chemical, 1994, vol. 19,issues 1–3, pp. 400–403.
Nomura, Tsuyoshi and Nakagava, Genkichi, Chem. Soc. Jpn., 1983, vol. 56, pp. 3632–3634.
Thornton, Mettler Toledo, Application Notes, Measurement of Conductivity and pH in Semiconductor HF Etching Solutions & Wastewater, 2008. http://us.mt.com/global/en/home/supportive_content/application_editorials/App-Note-THOR-Measurement-of-Conductivity-pH.rxHgAwXLlLnPBMDSzq—.MediaFileComponent.html/AN-Measurement_Conductivity__pH_0708.pdf.
Thornton, Mettler Toledo, Application Bulletin, Measurement of pH in Fluoride-Containing Processes, 2004. http://my-mt.com/thornton/pdf_files/bulletins/Hydrofluoric_Acid.pdf.
Mishchenko, K.P. and Ravdel’, A.A., Kratkii spravochnik fiziko-khimicheskikh velichin (Concise Reference Book of Physicochemical Quantities), lLeningrad: Khimiya, 1972.
Stock, J.T., Purdy, W.C., and Garcia, L.M., Chem. Rev., 1958, vol. 58, pp. 611–626.
Kazak, A.S., Rodionova, S.A., Trofimov, M.A., and Pendin, A.A., Elektrokhimiya, 1996, vol. 32, no. 7, pp. 887–890.
Trofimov, M.A., Puzanov, V.V., Kazak, A.S., and Pendin, A.A., in Ionnyi obmen i ionometriya: Mezhvuzovskii sbornik statei (Ion Exchange and Ionometry: Interuniversity Coll.), St. Petersburg: St-Peterburg. Gos. Univ., 2000, issue 10, pp. p215–228.
Karpukhina, N.G., Study of the Bulk and Electrode Properties of Halogen-Containing Alkali Metal Silicate Glasses, Cand. Sci. Dissertation, St.-Petersburg, 2001.
Ives, D. and Janz, G., Reference Electrodes: Theory and Practice, lNew York: Academic, 1961.
Bobrov, V.S., Zh. Prikl. Khim., 1978, vol. 51, no. 10, pp. p2237–2242.
Bach, H., Baucke, F.G.K., and Krause, D., Electrochemistry of Glasses and Glass Melts, Including Glass Electrodes, lBerlin: Springer, 2001.
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Original Russian Text © A.A. Kiprianov, N.M. Pankratova, I.A. Ponomarev, 2011, published in Zhurnal Prikladnoi Khimii, 2011, Vol. 84, No. 11, pp. 1797–1803.
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Kiprianov, A.A., Pankratova, N.M. & Ponomarev, I.A. Potentiometric pH sensors for measurements in fluoride-containing solutions. Russ J Appl Chem 84, 1883–1889 (2011). https://doi.org/10.1134/S1070427211110085
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DOI: https://doi.org/10.1134/S1070427211110085