Skip to main content
SpringerLink
Log in

Electrodialytic recovery of cobalt(II) with liquid membranes based on di(2-ethylhexyl)phosphoric acid

  • Applied Electrochemistry and Corrosion Protection of Metals
  • Published:
Russian Journal of Applied Chemistry Aims and scope Submit manuscript

Abstract

Electrodialytic transfer of cobalt(II) from sulfuric acid solutions across liquid membranes containing di(2-ethylhexyl)phosphoric acid with addition of tri-n-octylamine in 1,2-dichloroethane was studied, with the metal electrodeposited from dilute solutions of various acids. The influence exerted by the electrodialysis current density and by the composition of aqueous solutions and liquid membranes on the rate of cobalt(II) transport and electrodeposition was examined.

This is a preview of subscription content, log in via an institution to check access.

Access this article

Log in via an institution

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Institutional subscriptions

Similar content being viewed by others

References

  1. Perel’man, F.M. and Zvorykin, A.Ya., Kobal’t i nikel’ (Cobalt and Nickel), Moscow: Nauka, 1975.

    Google Scholar 

  2. Yagodin, G.A., Kagan, S.Z., Tarasov, V.V., et al., Osnovy zhidkostnoi ekstraktsii (Fundamentals of Liquid Extraction), Yagodin, G.A., Ed., Moscow: Khimiya, 1981.

    Google Scholar 

  3. Ivakhno, S.Yu. and Yurtov, E.V., Membrannaya ekstraktsiya. Itogi nauki i tekhniki. Neorganicheskaya khimiya (Membrane Extraction, Advances of Science and Technology: Inorganic Chemistry), Moscow: VINITI, 1990, vol. 18.

    Google Scholar 

  4. Lisovskii, V.B., Gubin, A.F., and Volkovskaya, E.I., Fiziko-khimicheskie problemy khimicheskikh proizvodstv (Physicochemical Problems of Chemical Industries), Moscow: Mosk. Khim.-Tekhnol. Inst., 1990, p. 64.

    Google Scholar 

  5. Chaudry, M.A., Malik, M.T., and Ali, A., Separ. Sci. Technol., 1990, vol. 25, nos. 11–12, pp. 1161–1174.

    Article  CAS  Google Scholar 

  6. Huang, T.C. and Tsai, T.H., J. Chem. Eng. Jpn, 1991, vol. 24, no. 1, pp. 126–132.

    Article  CAS  Google Scholar 

  7. Prakorn, R., Eakkapit, S., Weerawat, P., et al., Korean J. Chem. Eng., 2006, vol. 23, no. 1, pp. 117–123.

    Article  CAS  Google Scholar 

  8. Verbeken, K., Vanheule, B., Pinoy, L., and Verhaege, M., J. Chem. Technol. Biotechnol., 2009, vol. 84, no. 5, pp. 711–715.

    Article  CAS  Google Scholar 

  9. Wodzki, R. and Sionkowski, G., Separ. Sci. Technol., 1996, vol. 31, no. 11, pp. 1541–1553.

    Article  CAS  Google Scholar 

  10. Leon, G. and Guzman, M.A., Desalination, 2004, vol. 162, pp. 211–215.

    Article  CAS  Google Scholar 

  11. Gega, J., Walkowiak, W., and Gaida, B., Separ. Purif. Technol., 2001, vols. 22–23, pp. 551–558.

    Article  Google Scholar 

  12. Sadyrbaeva, T.Zh. and Purin, B.A., Khim. Tekhnol., 2000, no. 11, pp. 23–27.

  13. Sadyrbaeva, T.Zh., Zh. Prikl. Khim., 2009, vol. 82, no. 6, pp. 952–956.

    Google Scholar 

  14. Sadyrbaeva, T.Zh., Zh. Prikl. Khim., 2007, vol. 80, no. 11, pp. 1839–1844.

    Google Scholar 

  15. Marchenko, Z., Fotometricheskoe opredelenie elementov (Photometric Determination of Elements), lMoscow: Mir, 1971.

  16. Khol’kin, A.I., Belova, V.V., Pashkov, G.L., et al., Sovremennye problemy khimii i tekhnologii ekstraktsii (Modern Problems of Chemistry and Extraction Technology), Moscow, 1999, vol. 1, pp. 112–135.

    Google Scholar 

  17. Gindin, L.M., Ekstraktsionnye protsessy i ikh primenenie (Extraction Processes and Their Application), lMoscow: Nauka, 1984.

  18. Golubev, V.N. and Purin, B.A., Doklady Akad. Nauk SSSR. 1977, vol. 232, no. 6, pp. 1340–1342.

    CAS  Google Scholar 

Download references

Author information

Authors and Affiliations

  1. Institute of Inorganic Chemistry, Riga Technical University, Salaspils, Latvia

    T. Zh. Sadyrbaeva

Authors
  1. T. Zh. Sadyrbaeva
    View author publications

    You can also search for this author in PubMed Google Scholar

Additional information

Original Russian Text © T.Zh. Sadyrbaeva, 2011, published in Zhurnal Prikladnoi Khimii, 2011, Vol. 84, No. 11, pp. 1785–1791.

Rights and permissions

Reprints and permissions

About this article

Cite this article

Sadyrbaeva, T.Z. Electrodialytic recovery of cobalt(II) with liquid membranes based on di(2-ethylhexyl)phosphoric acid. Russ J Appl Chem 84, 1871–1877 (2011). https://doi.org/10.1134/S1070427211110061

Download citation

  • Received:

  • Published:

  • Issue Date:

  • DOI: https://doi.org/10.1134/S1070427211110061

Keywords

Search

Navigation