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Synthesis of cationic poly-1,3-pentadiene under the action of Gustavson complex

  • Organic Synthesis and Industrial Organic Chemistry
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Abstract

Polymerization of 1,3-pentadiene was performed using the Gustavson complex (AlCl2.xylene.0.5HCl) at a nearly full conversion of the monomer. The possibility of control over molecular characteristics of the polymer was demonstrated. Recommendations for application of the poly-1,3-pentadiene synthesized are given.

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Authors and Affiliations

  1. Institute of Ecology of the Volga River Basin, Russian Academy of Sciences, Togliatti, Samara oblast, Russia

    V. A. Rozentsvet, V. G. Kozlov, N. A. Korovina & V. P. Ivanova

  2. Lebedev Synthetic Rubber Research Institute, St. Petersburg, Russia

    V. A. Rozentsvet, V. G. Kozlov, N. A. Korovina & V. P. Ivanova

Authors
  1. V. A. Rozentsvet
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  2. V. G. Kozlov
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  3. N. A. Korovina
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  4. V. P. Ivanova
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Additional information

Original Russian Text © V.A. Rozentsvet, V.G. Kozlov, N.A. Korovina, V.P. Ivanova, 2011, published in Zhurnal Prikladnoi Khimii, 2011, Vol. 84, No. 9, pp. 1499–1504.

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Rozentsvet, V.A., Kozlov, V.G., Korovina, N.A. et al. Synthesis of cationic poly-1,3-pentadiene under the action of Gustavson complex. Russ J Appl Chem 84, 1549–1554 (2011). https://doi.org/10.1134/S1070427211090151

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  • DOI: https://doi.org/10.1134/S1070427211090151

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