Abstract
Fundamental kinetic aspects of the decomposition of mixtures and double salts of ammonium nitrate and ammonium sulfate were studied. The effect of water and sulfuric acid additives on the thermal decomposition rate of ammonium nitrate and sulfate mixtures was examined. The constant of proton exchange between nitric acid and the sulfate anion in molten ammonium nitrate was estimated.
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Chernyshev, A.K., Levin, B.V., and Konvisar, L.V., Ammiachnaya selitra i udobreniya na ee osnove (Ammonia Saltpeter and Fertilizers on Its Base), Moscow: Infokhim, 2003.
Rubtsov, Yu.I., Kazakov, A.I., Morozkin, S.Yu., et al., Zh. Prikl. Khim., 1984, vol. 57, no. 9, pp. 1926–1929.
Rubtsov, Yu.I., Samoilenko, N.G., Kazakov, A.I., and Manelis, G.B., 27th Int. Annual Conf. of ICT “Energetic Materials — Technology, Manufacturing and Prosessing,” Karlsruhe, June 25–28, 1996, Karlsruhe, 1996, pp. 106.1–106.11.
Strizhevskii, I.I., Bezopasnost’ Truda Prom-sti, 1984, no. 5, pp. 49–51.
Manelis, G.B., Nazin, G.M., Rubtsov, Yu.I., and Strunin, V.A., Termicheskoe razlozhenie i gorenie vzryvchatykh veshchestv i porokhov (Thermal Decomposition and Combustion of Explosives and Powders), Moscow: Nauka, 1996.
Rubtsov, Yu.I., Kazakov, A.I., Rustambekov, M.K., et al., Zh. Prikl. Khim., 2005, vol. 78, no. 11, pp. 1827–1832.
Rubtsov, Yu.I., Strizhevskii, I.I., Kazakov, A.I., et al., Zh. Prikl. Khim., 1989, vol. 62, no. 10, pp. 2169–2174.
Gal’perin, L.N., Kolesov, Yu.R., Mashkinov, L.B., et al., Materialy VI Vsesoyuznoi konferentsii po kalorimetrii, Tbilisi, 17–19 sentyabrya 1973 goda (Proc. VI All-Union Conf. on Calorimetry, Tbilisi, September 17–19, 1973), Tbilisi, 1973, pp. 539–543.
Albert, A. and Serjeant, E., Ionization Constants of Acids and Bases, London: Methuen, New York: Wiley, 1962.
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Original Russian Text © A.I. Kazakov, O.G. Ivanova, L.S. Kurochkina, N.A. Plishkin, 2011, published in Zhurnal Prikladnoi Khimii, 2011, Vol. 84, No. 9, pp. 1465–1472.
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Kazakov, A.I., Ivanova, O.G., Kurochkina, L.S. et al. Kinetics and mechanism of thermal decomposition of ammonium nitrate and sulfate mixtures. Russ J Appl Chem 84, 1516–1523 (2011). https://doi.org/10.1134/S1070427211090102
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DOI: https://doi.org/10.1134/S1070427211090102