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Analytical form of concentration dependence of thermodynamic functions of liquid metal system sodium-mercury

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Abstract

Dependence of integral molar excess Gibbs energy ΔG exc of liquid alloys of a system sodium-mercury on a composition was developed with the help of series of polynomial models and also coefficients of sodium activity at infinite dilution γNa/∞ were estimated.

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References

  1. Diagrammy sostoyaniya dvoinykh metallicheskikh sistem (Diagrams of Binary Metallic Systems), Lyakishev, N.P., Ed., Moscow: Mashinostroenie, 1997.

    Google Scholar 

  2. Borgstedt, H.U. and Mathews, C.K., Applied Chemistry of the Alkali Metals, New York: Plenum, Press, 1987.

    Google Scholar 

  3. Borgstedt, H.U. and Peric, Z., Liquid Metal Systems: Material, Behavior, and Physical Chemistry in Liquid Metal Systems, Borgstedt, H.U., Ed., New York: Plenum, Press, 1995, pp. 363–368.

    Google Scholar 

  4. Morachevskii, A.G., Shesterkin, I.A., Busse-Machukas, V.B., et al., Natrii: Svoistva, proizvodstvo, primenenie (Sodium: Properties, Production, Application), Morachevskii, A.G., Ed., St. Petersburg: Khimiya, 1992.

    Google Scholar 

  5. Kozin, L.F., Fiziko-khimiya i metallurgiya vysokochistoi rtuti i ee splavov (Physicochemistry and Metallurgy of High-Purity Mercury and Its Alloys), Kiev: Naukova Dumka, 1992.

    Google Scholar 

  6. Morachevskii, A.G. and Butukhanova, T.V., Zh. Prikl. Khim., 2010, vol. 83, no. 4, pp. 559–563.

    Google Scholar 

  7. Morachevskii, A.G. and Butukhanova, T.V., Zh. Prikl. Khim., 2010, vol. 83, no. 8. pp. 1396-1399.

  8. Morachevskii, A.G. and Butukhanova, T.V., Zh. Prikl. Khim., 2010, vol. 83, no. 11, pp. 1917–1918.

    Google Scholar 

  9. Morachevskii, A.G. and Butukhanova, T.V., Zh. Prikl. Khim., 2011, vol. 84, no. 4, pp. 566–570.

    Google Scholar 

  10. Bykova, M.A. and Morachevskii, A.G., Zh. Prikl. Khim., 1973, vol. 46, no. 2, pp. 312–316.

    CAS  Google Scholar 

  11. Iverson, M.L. and Recht, H.L., J. Chem. Eng. Data, 1967, vol. 12, pp. 262–265.

    Article  CAS  Google Scholar 

  12. Morachevskii, A.G., Termodinamika rasplavlennykh metallicheskikh i solevykh sistem (Thermodynamics of Molten Metal and Salt Systems), Moscow: Metallurgiya, 1987.

    Google Scholar 

  13. Morachevskii, A.G. and Sladkov, I.B., Termodinamicheskie raschety v metallurgii: Sprav. (hermodynamic Calculations in Metallurgy. Handbook), Moscow: Metallurgiya, 1993.

    Google Scholar 

  14. Morachevskii, A.G. and Kokhatskaya, M.S., Prikladnaya khimicheskaya termodinamika (Applied Chemical Thermodynamics), St. Petersburg: Izd. Politekhn. Inst, 2008.

    Google Scholar 

  15. Morachevskii, A.G. and Erofeev, K.B., Zh. Prikl. Khim., 2000, vol. 73, no. 6, pp. 1032–1034.

    CAS  Google Scholar 

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Authors and Affiliations

  1. St. Petersburg State Polytechnic University, St. Petersburg, Russia

    A. G. Morachevskii & T. V. Butukhanova

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  1. A. G. Morachevskii
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  2. T. V. Butukhanova
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Original Russian Text © A.G. Morachevskii, T.V. Butukhanova, 2011, published in Zhurnal Prikladnoi Khimii, 2011, Vol. 84, No. 8, pp. 1381–1383.

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Morachevskii, A.G., Butukhanova, T.V. Analytical form of concentration dependence of thermodynamic functions of liquid metal system sodium-mercury. Russ J Appl Chem 84, 1442–1444 (2011). https://doi.org/10.1134/S1070427211080271

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  • DOI: https://doi.org/10.1134/S1070427211080271

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