Abstract
Commercial microheterogeneous titanium catalyst in the step of its preliminary formation was subjected to hydrodynamic action by circulation in a tubular diffuser-confuser apparatus. As a result of such treatment, the Mooney viscosity of the high-molecular-weight polyisoprene prepared in the presence of this catalyst becomes more stable.
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Sinteticheskii kauchuk (Synthetic Rubber), Garmonov, I.V., Ed., Leningrad: Khimiya, 1983.
Kirpichnikov, P.A., Beresnev, V.V., and Popova, L.M., Al’bom tekhnologicheskikh skhem osnovnykh proizvodstv promyshlennosti sinteticheskogo kauchuka (Album of Flowsheets of the Main Production Processes in the Synthetic Rubber Industry), Leningrad: Khimiya, 1986.
Zakharov, V.P., Berlin, A.A., Monakov, Yu.B., and Deberdeev, R.Ya., Fiziko-khimicheskie osnovy protekaniya bystrykh zhidkofaznykh protsessov (Physicochemical Principles of Fast Liquid-Phase Processes), Moscow: Nauka, 2008.
Monakov, Yu.B., Sigaeva, N.N., and Urazbaev, V.N., Active Sites of Polymerization: Multiplicity: Stereospecific and Kinetic Heterogeneity, Leiden: Brill Academic, 2005.
Monakov, Yu.B. and Tolstikov, G.A., Kataliticheskaya polimerizatsiya 1,3-dienov (Catalytic Polymerization of 1,3-Dienes), Moscow: Nauka, 1990.
RF Patent 2036509.
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Original Russian Text © Yu.V. Morozov, I.Sh. Nasyrov, V.P. Zakharov, V.Z. Mingaleev, Yu.B. Monakov, 2011, published in Zhurnal Prikladnoi Khimii, 2011, Vol. 84, No. 8, pp. 1373–1376.
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Morozov, Y.V., Nasyrov, I.S., Zakharov, V.P. et al. Enhancement of the activity of the titanium catalyst for isoprene polymerization by improving the step of active site formation. Russ J Appl Chem 84, 1434–1437 (2011). https://doi.org/10.1134/S1070427211080258
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DOI: https://doi.org/10.1134/S1070427211080258