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Polymerization of 1,3-butadiene under the action of cobalt catalyst in an aliphatic solvent with formation of polymers suitable for commercial use

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Abstract

Polymerization of 1,3-butadiene in an n-hexane solution in the presence of the catalyltic complex cobalt 2-ethylhexanoate-diisobutylaluminum chloride-water-isoprene was studied. The conditions were found for preparing cis-polybutadiene with the molecular-weight distributions ensuring the physicomechanical parameters required for commercial applications.

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Authors and Affiliations

  1. Sintel Public Joint-Stock Company, St. Petersburg, Russia

    L. V. Smirnova, I. I. Khamitov & E. N. Kropacheva

Authors
  1. L. V. Smirnova
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  2. I. I. Khamitov
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  3. E. N. Kropacheva
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Original Russian Text © L.V. Smirnova, I.I. Khamitov, E.N. Kropacheva, 2011, published in Zhurnal Prikladnoi Khimii, 2011, Vol. 84, No. 7, pp. 1221–1225.

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Smirnova, L.V., Khamitov, I.I. & Kropacheva, E.N. Polymerization of 1,3-butadiene under the action of cobalt catalyst in an aliphatic solvent with formation of polymers suitable for commercial use. Russ J Appl Chem 84, 1292–1296 (2011). https://doi.org/10.1134/S1070427211070305

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  • DOI: https://doi.org/10.1134/S1070427211070305

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