Skip to main content
Log in

Unsaturated oligomers with perfluorinated segments as modifiers of surface properties of powder UV-curable oligoether dimethacrylate coatings

  • Macromolecular Compounds and Polymeric Materials
  • Published:
Russian Journal of Applied Chemistry Aims and scope Submit manuscript

Abstract

Perfluorooligoetherbis(urethane)ethoxystyrenes were prepared by the reaction of fluorinated oligoetherdiols (Z-DOL trade names), hexamethylene isocyanate, and p-hydroxyethoxystyrene. The performance of these products as agents making more hydrophobic the surface of coatings based on solid UV-curable oligoether dimethacrylate was studied. The physicomechanical properties of the composite coatings were examined in relation to the structure of styrene derivatives and to the composition of the powder formulations.

This is a preview of subscription content, log in via an institution to check access.

Access this article

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Similar content being viewed by others

References

  1. Yakovlev, A.D., Khimiya i tekhnologiya lakokrasochnykh pokrytii (Chemistry and Technology of Paint-and-Varnish Coatings), St. Petersburg: Khimizdat, 2010.

    Google Scholar 

  2. Sangermano, M., Bongiovanni, R., Malucelli, G., et al., Prog. Org. Coat., 2006, vol. 57, pp. 44–49.

    Article  CAS  Google Scholar 

  3. Bongiovanni, R., Malucelli, G., and Priola, A., J. Colloid Interface Sci., 1995, vol. 171, pp. 283–287.

    Article  CAS  Google Scholar 

  4. Graham, P., Stone, M., Thorpe, A., et al., J. Fluorine Chem., 2000, vol. 104, pp. 29–36.

    Article  CAS  Google Scholar 

  5. Ming, W., Melis, F., Grampel, R.D., et al., Prog. Org. Coat., 2003, vol. 48, pp. 316–321.

    Article  CAS  Google Scholar 

  6. Bongiovanni, R., Malucelli, G., Sangermano, M., and Priola, A., J. Fluorine Chem., 2004, vol. 125, pp. 345–351.

    Article  CAS  Google Scholar 

  7. Bongiovanni, R., Beamson, G., Mamo, A., et al., Polymer, 2000, vol. 41, pp. 409–414.

    Article  CAS  Google Scholar 

  8. Miao, H., Cheng, L., and Shi, W., Prog. Org. Coat., 2009, vol. 65, pp. 71–76.

    Article  CAS  Google Scholar 

  9. Sangermano, M., Bongiovanni, R., Priola, A., and Pospiech, D., J. Polym. Sci., Part A: Polym. Chem., 2005, vol. 43, pp. 4144–4150.

    Article  CAS  Google Scholar 

  10. Bongiovanni, R., Malucelli, G., Sangermano, M., and Priola, A., Prog. Org. Coat., 1999, vol. 36, pp. 70–78.

    Article  CAS  Google Scholar 

  11. Moshiashvili, V.V., Mashlyakovskii, L.N., Egorova, N.A., and Kuzina, N.G., Lakokras. Mater. Ikh Primen., 2007, no. 3, pp. 38–45.

  12. Moshiashvili, V.V., Mashlyakovskii, L.N., Egorova, N.A., et al., Lakokras. Mater. Ikh Primen., 2007, no. 4, pp. 37–44.

  13. Moshiashvili, V.V., Egorova, N.A., Kuzina, N.G., and Mashlyakovskii, L.N., Lakokras. Mater. Ikh Primen., 2007, no. 11, pp. 30–33.

  14. RF Patent 2404218.

  15. Yur’ev, Yu.K., Prakticheskie raboty po organicheskoi khimii (Practical Works in Organic Chemistry), Moscow: Mosk. Gos. Univ., 1957.

    Google Scholar 

  16. Potapova, V.M. and Ponomareva, S.V., Praktikum po organicheskoi khimii (Practical Course of Organic Chemistry), Moscow: Mir, 1979, vol. 1.

    Google Scholar 

  17. Karyakina, M.I., Ispytanie lakokrasochnykh materialov i pokrytii (Testing of Paint-and-Varnish Materials and Coatings), Moscow: Khimiya, 1988.

    Google Scholar 

  18. Frolov, Yu.G., Kurs kolloidnoi khimii: Poverkhnostnye yavleniya i dispersnye sistemy (Course of Colloid Chemistry: Surface Phenomena and Disperse Systems), Moscow: Khimiya, 1988.

    Google Scholar 

  19. Bongiovanni, R., De Meo, A., Pollicino, A., et al., React. Funct. Polym., 2008, vol. 68, pp. 189–200.

    Article  CAS  Google Scholar 

  20. Panshin, Yu.A., Malkevich, S.G., and Dunaevskaya, Ts.S., Ftoroplasty (Fluoroplastics), Leningrad: Khimiya, 1978.

    Google Scholar 

  21. Scheirs, J., Modern Fluoropolymers: High Performance Polymers for Diverse Applications, Wiley, 1997.

Download references

Author information

Authors and Affiliations

Authors

Additional information

Original Russian Text © I.V. Korolev, N.G. Kuzina, L.N. Mashlyakovskii, 2011, published in Zhurnal Prikladnoi Khimii, 2011, Vol. 84, No. 7, pp. 1175–1182.

Rights and permissions

Reprints and permissions

About this article

Cite this article

Korolev, I.V., Kuzina, N.G. & Mashlyakovskii, L.N. Unsaturated oligomers with perfluorinated segments as modifiers of surface properties of powder UV-curable oligoether dimethacrylate coatings. Russ J Appl Chem 84, 1246–1252 (2011). https://doi.org/10.1134/S1070427211070214

Download citation

  • Received:

  • Published:

  • Issue Date:

  • DOI: https://doi.org/10.1134/S1070427211070214

Keywords

Navigation