Skip to main content
SpringerLink
Log in

A catalytic process for preparation of thiophene from furan and hydrogen sulfide

  • Organic Synthesis and Industrial Organic Chemistry
  • Published:
Russian Journal of Applied Chemistry Aims and scope Submit manuscript

Abstract

Thiophene formation under various conditions from furan and H2S in the presence of γ-Al2O3, both unpromoted and promoted with transition metal oxides, was examined. The conditions enabling preparation of thiophene in a 95–98 mol% yield were determined.

This is a preview of subscription content, log in via an institution to check access.

Access this article

Log in via an institution

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Institutional subscriptions

Similar content being viewed by others

References

  1. Poluchenie i svoistva organicheskikh soedinenii sery (Preparation and Properties of Organosulfur Compounds), Belen’kii, L.I., Ed., Moscow: Khimiya, 1998.

    Google Scholar 

  2. Mashkina, A.V., Kataliz reaktsii organicheskikh soedinenii sery (Catalysis of Reactions of Organosulfur Compounds), Novosibirsk: Sib. Otd. Ross. Akad. Nauk, 2005.

    Google Scholar 

  3. Yur’ev, Yu.K., Uchen. Zap. Mosk. Gos. Univ., Ser. Khim., issue 79, 1945, pp. 1–183.

  4. BE Patent 1008868.

  5. BE Patent 623801.

  6. RF Patent 2263537.

  7. Mashkina, A.V. and Khairulina, L.N., Kinet. Katal., 2008, vol. 49, no. 2, pp. 258–265.

    Google Scholar 

  8. Li, Q., Xu, Y., Liu, C., and Kim, J., Catal. Lett., 2008, vol. 122, no. 2, pp. 354–358.

    Article  CAS  Google Scholar 

  9. Paukshtis, E.A., Infrakrasnaya spektroskopiya v geterogennom kislotno-osnovnom katalize (Infrared Spectroscopy in Heterogeneous Acid-Base Catalysis), Novosibirsk: Nauka, 1992.

    Google Scholar 

  10. Mashkina, A.V., Sulfur Rep., 1991, vol. 10, no. 4, pp. 279–388.

    Article  CAS  Google Scholar 

  11. Desiatov, I.V., Paukshtis, E.A., and Mashkina, A.V., React. Kinet. Catal. Lett., 1990, vol. 41, no. 1, pp. 85–88.

    Article  Google Scholar 

  12. Boreskov, G.K., Geterogennyi kataliz (Heterogeneous Catalysis), Moscow: Nauka, 1986.

    Google Scholar 

Download references

Author information

Authors and Affiliations

  1. Boreskov Institute of Catalysis, Siberian Division, Russian Academy of Sciences, Novosibirsk, Russia

    A. V. Mashkina

Authors
  1. A. V. Mashkina
    View author publications

    You can also search for this author in PubMed Google Scholar

Additional information

Original Russian Text © A.V. Mashkina, 2011, published in Zhurnal Prikladnoi Khimii, 2011, Vol. 84, No. 7, pp. 1152–1157.

Rights and permissions

Reprints and permissions

About this article

Cite this article

Mashkina, A.V. A catalytic process for preparation of thiophene from furan and hydrogen sulfide. Russ J Appl Chem 84, 1223–1228 (2011). https://doi.org/10.1134/S1070427211070172

Download citation

  • Received:

  • Published:

  • Issue Date:

  • DOI: https://doi.org/10.1134/S1070427211070172

Keywords

Search

Navigation