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Effect of temperature on thiocarbamide isomerization in concentrated aqueous solutions

  • Organic Synthesis and Industrial Organic Chemistry
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Abstract

The reaction of isomerization of thiocarbamide to ammonium thiocyanate in aqueous concentrated solutions at temperatures from 100 to 150°C was studied by UV and NMR spectroscopy, as well as by photocolorimetric and conductometric methods. The isomerization reaction rate constants, activation energy, and isomerization ratio were calculated.

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References

  1. Sokolovskii, E.V., Solov’ev, G.B., and Trenchikov, Yu.I., Indikatornye metody izucheniya neftegazonosnykh plastov (Indicator Methods for Oil and Gas Reservoir Studies), Moscow: Nedra, 1986.

    Google Scholar 

  2. Kharitonov, Yu.Ya, Ismail, M.A., Sarukhanov, M.A., et al., Zh. Neorg. Khim., 1988, vol. 33, no. 8, pp. 1961–1966.

    CAS  Google Scholar 

  3. Kharitonov, Yu.Ya, Ismail, M.A., Sarukhanov, M.A., et al., Zh. Neorg. Khim., 1988, vol. 33, no. 8, pp. 1967–1969.

    CAS  Google Scholar 

  4. Kharitonov, Yu.Ya, Ismail, M.A., Sarukhanov, M.A., et al., Zh. Neorg. Khim., 1988, vol. 33, no. 5, pp. 1343–1345.

    CAS  Google Scholar 

  5. Belevskii, S.F., Sarukhanov, M.A., Kharitonov, Yu.Ya., et al., Zh. Neorg. Khim., 1997, vol. 42, no. 3, pp. 502–509.

    CAS  Google Scholar 

  6. Belevskii, S.F., Kharitonov, Yu.Ya., Sarukhanov, M.A., et al., Zh. Neorg. Khim., 1997, vol. 42, no. 8, pp. 1263–1268.

    CAS  Google Scholar 

  7. Bershtein, I.Ya. and Kaminskii, Yu.L., Spektrofotometricheskii analiz v organicheskoi khimii (Spectrophotometric Analysis in Organic Chemistry), Leningrad: Khimiya, 1975.

    Google Scholar 

  8. Perfil’ev, V.A., Mishchenko, V.T., and Poluektov, N.S., Zh. Anal. Khim., 1985, vol. 40, pp. 1349–1351.

    Google Scholar 

  9. Urakaev, F.Kh. and Bazarov, L.Sh., Zh. Neorg. Khim., 2001, vol. 46, no. 1, pp. 54–55.

    CAS  Google Scholar 

  10. Moskalevich, V.L. and Lebedinskii, N.A., Vopr. Khim. Khim. Tekhnol., Kharkov: Kharkov. Univ, 1984, issue 74, pp. 23–26.

    Google Scholar 

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Authors and Affiliations

  1. Institute of Petroleum Chemistry, Siberian Branch, Russian Academy of Sciences, Tomsk, Russia

    L. K. Altunina, V. A. Kuvshinov, N. I. Rodionova, T. V. Petrenko & V. D. Ogorodnikov

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  1. L. K. Altunina
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  2. V. A. Kuvshinov
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  3. N. I. Rodionova
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  4. T. V. Petrenko
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  5. V. D. Ogorodnikov
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Original Russian Text © L.K. Altunina, V.A. Kuvshinov, N.I. Rodionova, T.V. Petrenko, V.D. Ogorodnikov, 2011, published in Zhurnal Prikladnoi Khimii, 2011, Vol. 84, No. 6, pp. 969–972.

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Altunina, L.K., Kuvshinov, V.A., Rodionova, N.I. et al. Effect of temperature on thiocarbamide isomerization in concentrated aqueous solutions. Russ J Appl Chem 84, 993–996 (2011). https://doi.org/10.1134/S1070427211060164

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  • DOI: https://doi.org/10.1134/S1070427211060164

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