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A study of the kinetics and mechanism of amidation of 4-nitrobenzoic acid with ammonia, catalyzed by boric acid in the presence of polyethylene glycol PEG-400

  • Organic Synthesis and Industrial Organic Chemistry
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Abstract

Kinetics of the reaction of 4-nitrobenzoic acid with ammonia, catalyzed by the system constituted by boric acid and PEG-400 poly(ethylene glycol), was studied. A catalysis mechanism was suggested, which consists in original synthesis of incomplete polyethylene glycol borate esters, formation on their basis of 4-nitrobenzoic acid borate esters, and their further amidation with ammonia.

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References

  1. Shteinberg, L.Ya., Zh. Org. Khim., 2003, vol. 39, no. 7, pp. 1033–1035.

    Google Scholar 

  2. Shteinberg, L.Ya., Zh. Prikl. Khim., 2005, vol. 78, no. 10, pp. 1745–1747.

    Google Scholar 

  3. Shteinberg, L.Ya., Zh. Prikl. Khim., 2006, vol. 79, no. 8, pp. 1296–1299.

    Google Scholar 

  4. Shteinberg, L.Ya., Zh. Prikl. Khim., 2009, vol. 82, no. 4, pp. 619–623.

    Google Scholar 

  5. Panchenkov, G.M. and Lebedev, V.P., Khimicheskaya kinetika i kataliz: Uchebnoe pocobie dlya vuzov (Chemical Kinetics and Catalysis: Textbook for Higher School Institutions), Moscow: Khimiya, 1985.

    Google Scholar 

  6. Bonchev, P., Kompleksoobrazovanie i kataliticheskaya aktivnost’ (Complexation and Catalytic Activity), Moscow: Mir, 1975.

    Google Scholar 

  7. Nelson, P. and Pelter, A., J. Chem. Soc., 1965, vol. 9, pp. 5142–5144.

    Article  Google Scholar 

  8. Shvarts, E.M., Vzaimodeistvie bornoi kisloty so spirtami i oksikislotami (Interaction of Boric Acid with Alcohols and Oxy Acids), Riga: Zinatne, 1990.

    Google Scholar 

  9. Pelter, A. and Levitt, T.E., Tetrahedron, 1970, vol. 26, no. 6, pp. 1539–1544.

    Article  CAS  Google Scholar 

  10. Shmid, R. and Sapunov, V.N., Neformal’naya kinetika (Informal Kinetics), Moscow: Mir, 1986.

    Google Scholar 

  11. Host Guest Complex Chemistry: Macrocycles: Synthesis, Structures, Applications, Vogtle, F. and Weber, E., Eds., Berlin: Springer, 1985.

    Google Scholar 

  12. Ford, W.T., In Polymeric Reagents and Catalysts, ACS Symposium Series, 1986, vol. 308, pp 1–16

    Article  CAS  Google Scholar 

  13. Pomogailo, A.D., Polimernye immobilizovannye metallokompleksnye katalizatory (Polymeric Immobilized Metal-Complex Catalysts), Moscow: Nauka, 1988.

    Google Scholar 

  14. Mezhfaznyi kataliz: Khimiya, katalizatory i primenenie (Interphase Catalysis: Cmemistry, Catalysts, and Application), Starks, Ch.M., Ed., Moscow: Khimiya, 1991.

    Google Scholar 

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Authors and Affiliations

  1. Institute of Chemical Technology and Industrial Ecology, Scientific and Technical Institution, Rubezhnoe, Lugansk oblast, Ukraine

    L. Ya. Shteinberg

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  1. L. Ya. Shteinberg
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Original Russian Text © L.Ya. Shteinberg, 2011, published in Zhurnal Prikladnoi Khimii, 2011, Vol. 84, No. 5, pp. 785–789.

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Shteinberg, L.Y. A study of the kinetics and mechanism of amidation of 4-nitrobenzoic acid with ammonia, catalyzed by boric acid in the presence of polyethylene glycol PEG-400. Russ J Appl Chem 84, 815–819 (2011). https://doi.org/10.1134/S1070427211050132

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  • DOI: https://doi.org/10.1134/S1070427211050132

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