Abstract
Results of numerical modeling of the kinetics of reaction of binding of nitrogen at mechanochemical disintegration of water solutions are illustrated. Experimental data of kinetics of more than fifty reactions which in many cases are different from Arrhenius kinetics were used in calculations. It is found that the main channel of nitrogen fixation is the formation of nitrocompounds, but in the presence of small amount of hydrogen the change to the channel of ammonia formation becomes possible.
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Original Russian Text © Z.S. Salimov, U.S. Baltaev, A.M. Khurmamatov, N.Kh. Yuldashev, O.R. Obdurakhmonov, 2010, published in Khimicheskaya Promyshlennost’, 2010, Vol. 87, No. 8, pp. 411–418.
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Salimov, Z.S., Baltaev, U.S., Khurmamatov, A.M. et al. Results of investigation of the structure and physicochemical properties of fibrous dust. Russ J Appl Chem 84, 559–564 (2011). https://doi.org/10.1134/S1070427211030396
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DOI: https://doi.org/10.1134/S1070427211030396