Abstract
Radical telomerization of perfluoropoly(oxamethylene iodides) with trifluoroethylene was studied. Based on the 1H and 19F NMR spectroscopic data, the pathways for olefin addition to the iodide in the initial and subsequent stages were examined.
References
Walling C. and Huyser E.S., in Organic Reactions, Cope, A.C., Ed., New York: Wiley, 1963, vol. 13, pp. 91–149.
Ankudinov, A.K., Ryazanova, R.M., and Sokolov, S.V., Zh. Org. Khim., 1974, vol. 10, no. 12, pp. 2503–2507.
Sianesi, D., Pasetti, A., and Corti, C., Makromol. Chem., 1965, no. 86, pp. 308–311.
Haszeldine, R.N. and Steele, B.R., J. Chem. Soc., 1954, pp. 3747–3751.
Emel’yanov, G.A., Polyanskii, V.I., and Berenblit, V.V., Zh. Org. Khim., 1994, vol. 30, no. 8, pp. 1266–1270.
Author information
Authors and Affiliations
Additional information
Original Russian Text © G.A. Emel’yanov, V.M. Rodin, D.P. Blinov, V.V. Berenblit, 2011, published in Zhurnal Prikladnoi Khimii, 2011, Vol. 84, No. 2, pp. 333–337.
Rights and permissions
About this article
Cite this article
Emel’yanov, G.A., Rodin, V.M., Blinov, D.P. et al. Telomerization of perfluoropoly(oxamethylene iodides) with trifluoroethylene. Russ J Appl Chem 84, 329–333 (2011). https://doi.org/10.1134/S1070427211020285
Received:
Published:
Issue Date:
DOI: https://doi.org/10.1134/S1070427211020285