Skip to main content
Log in

Polymerization of isoprene on a modified “neodymium” catalytic system

  • Macromolecular Chemistry and Polymeric Materials
  • Published:
Russian Journal of Applied Chemistry Aims and scope Submit manuscript

Abstract

Polymerization of isoprene using the catalytic system NdCl3·3i-C3H7OH-Al(i-C4H9)3 modified with methylalumoxane was studied. The kinetic parameters of the process and the molecular characteristics of the polyisoprene obtained were determined.

This is a preview of subscription content, log in via an institution to check access.

Access this article

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Similar content being viewed by others

References

  1. Shen, Z., Ouyang, J., Wang, F., et al., J. Polym. Sci., 1980, vol. 18, pp. 3345–3357.

    Google Scholar 

  2. Yang, J., Hu, J., Feng, S., et al., Sci. Sin., 1980, vol. 23, no. 6, pp. 734–744.

    CAS  Google Scholar 

  3. Hsieh, H. and Yeh, H., Rubb. Chem. Technol., 1985, vol. 58, no. 1, pp. 117–145.

    CAS  Google Scholar 

  4. Kornev, V.A., Makeeva, A.R., Morozov, Yu.L., and Gur’eva, E.S., Kauchuk Rezina, 1986, no. 4, pp. 12–14.

  5. RF Patent 2091400.

  6. Nasyrov, I.Sh., Morozov, Yu.V., Faizova, V.Yu., et al., Abstracts of Papers, Kauchuk i Rezina — 2010 (Rubber-2010), Moscow, April 19–22, 2010, pp. 124–125.

  7. Bazhenov, Yu.P., Nasyrov, I.Sh., and Petrunina, A.V., in Rezinovaya promyshlennost’: Syr’e, materialy, tekhnologii (Rubber Industry: Initial Substances, Materials, Technologies), Moscow, May 16–20, 2005, pp. 2–7.

  8. RF Patent 2061546.

  9. Dong, W. and Masuda, T., J. Polym. Sci., 2002, vol. 40, pp. 1838–1844.

    CAS  Google Scholar 

  10. Dong, W., Endo, K., and Masuda, T., Macromol. Chem. Phys., 2003, vol. 204, pp. 104–110.

    Article  CAS  Google Scholar 

  11. RF Patent. 2220909.

  12. Ermakov, Yu.I. and Zakharov, V.A., Usp. Khim., 1972, vol. 41, no. 3, pp. 377–409.

    CAS  Google Scholar 

  13. Chirkov, L.M., Matkovskii, P.E., and D’yachkovskii, F.S., Polimerizatsiya na kompleksnykh metalloorganicheskikh katalizatorakh (Polymerization on Complex Organometallic Catalysts), Moscow: Khimiya, 1976.

    Google Scholar 

  14. Ren, C., Li, G., Dong, W., et al., Polymer, 2007, vol. 48, pp. 2470–2474.

    Article  CAS  Google Scholar 

  15. Bodrova, V.S., Piskareva, E.P., Shelokhneva, L.F., and Poletaeva, I.A., Vysokomol. Soedin., Ser. A, 1998, vol. 40, no. 11, pp. 1741–1749.

    CAS  Google Scholar 

  16. Li, G., Ren, C., Dong, W., et al., Chin. J. Polym. Sci., 2010, vol. 28, no. 2, pp. 157–164.

    CAS  Google Scholar 

  17. Chen, W. and Wang, F., Sci. China, 2009, vol. 52, pp. 1520–1543.

    Article  CAS  Google Scholar 

Download references

Author information

Authors and Affiliations

Authors

Additional information

Original Russian Text © I.G. Akhmetov, A.M. Vagizov, 2010, published in Zhurnal Prikladnoi Khimii, 2010, Vol. 83, No. 12, pp. 2056–2059.

Rights and permissions

Reprints and permissions

About this article

Cite this article

Akhmetov, I.G., Vagizov, A.M. Polymerization of isoprene on a modified “neodymium” catalytic system. Russ J Appl Chem 83, 2182–2185 (2010). https://doi.org/10.1134/S1070427210120219

Download citation

  • Received:

  • Published:

  • Issue Date:

  • DOI: https://doi.org/10.1134/S1070427210120219

Keywords

Navigation