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Thermodynamic characterization of the amphoterism of oxides M2O3 (M = As, Sb, Bi) and Their hydrates in aqueous media

  • Physicochemical Studies of Systems and Processes
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Abstract

Thermodynamic method was used to calculate, taking into account the formation of hydroxo complexes, the effect of the pH value on the molar solubility of M2O3 solid oxides and their hydrates at 25°C and the constants of acid-base equilibria in aqueous media for crystalline oxides and dissolved hydroxides M(OH)3, where M = As, Sb, Bi.

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Original Russian Text © E.V. Shkol’nikov, 2010, published in Zhurnal Prikladnoi Khimii, 2010, Vol. 83, No. 12, pp. 1993–2000.

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Shkol’nikov, E.V. Thermodynamic characterization of the amphoterism of oxides M2O3 (M = As, Sb, Bi) and Their hydrates in aqueous media. Russ J Appl Chem 83, 2121–2127 (2010). https://doi.org/10.1134/S1070427210120104

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  • DOI: https://doi.org/10.1134/S1070427210120104

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