Abstract
Condensation of ortho-aminothiophenol with 2-thenoyl chloride in 1-methyl-2-pyrrolidone was used to synthesize 2-(2′-thienyl)benzothiazole. Its reactions of electrophilic (nitration, bromination, oxymethylation, formylation, acylation) and radical (nitration, arylation) substitution were studied.
This is a preview of subscription content, log in via an institution to check access.
Similar content being viewed by others
References
Belen’kii, L.I., Cheskis, M.A., Zvolinskii, V.P., and Obukhov, A.E., Khim. Geterotsikl. Soedin., 1986, no. 6, pp. 826–831.
Bogert, M.T. and Stull, A., J. Am. Chem. Soc., 1926, vol. 48, no. 2, pp. 248–251.
Emerson, W.S. and Patrick, T.M., J. Org. Chem., 1949, vol. 14, no. 3, pp. 790–796.
Capitan-Vallvey, L.F. and Espinosa, P., Polyhedron, 1983, vol. 2, no. 11, pp. 1147–1153.
El’chaninov, M.M., Oleinikova, L.Ya., and Simonov, A.M., Khim. Geterotsikl. Soedin., 1979, no. 8, pp. 1047–1049.
Kornilov, M.Yu., Ruban, E.M., Fedchuk, V.N., et al., Zh. Org. Khim., 1973, vol. 9, no. 12, pp. 2577–2582.
El’chaninov, M.M., Simonov, A.M., and Oleinikova, L.Ya., Khim. Geterotsikl. Soedin., 1983, no. 10, pp. 1311–1313.
Gardner, P.D., J. Am. Chem. Soc., 1951, vol. 76, pp. 4550–4554.
Dunn, G.L., Actor, P., and Di Pasquo, V.J., J. Med. Chem., 1966, vol. 9, no. 5, pp. 751–753.
Author information
Authors and Affiliations
Additional information
Original Russian Text © A.A. Aleksandrov, M.M. El’chaninov, 2010, published in Zhurnal Prikladnoi Khimii, 2010, Vol. 83, No. 9, pp. 1504–1508.
Rights and permissions
About this article
Cite this article
Aleksandrov, A.A., El’chaninov, M.M. Synthesis and some transformations of 2-(2′-thienyl)benzothiazole. Russ J Appl Chem 83, 1602–1606 (2010). https://doi.org/10.1134/S1070427210090181
Received:
Published:
Issue Date:
DOI: https://doi.org/10.1134/S1070427210090181