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Mechanism of formation, structure, and properties of heat-resistant network polymers prepared by thermal curing of Rolivsans

  • Macromolecular Compounds and Polymeric Materials
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Abstract

The mechanism of structural transformation of divinylaromatic formulations containing methacrylates of secondary aromatic alcohols and diols into heat-resistant and strong glassy network polymers was examined. The structure and properties of the products were studied. The Rolivsans prepared demonstrate the possibility of chemical construction of high-temperature thermosets in which molecules with thermally stable ether groups and labile ester groups, providing excellent process properties of the formulation in the low-temperature step of the reactive forming, are capable of transforming into heat-resistant network polymers.

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Authors and Affiliations

  1. Institute of Macromolecular Compounds, Russian Academy of Sciences, St. Petersburg, Russia

    B. A. Zaitsev & I. D. Shvabskaya

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  1. B. A. Zaitsev
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  2. I. D. Shvabskaya
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Original Russian Text © B.A. Zaitsev, I.D. Shvabskaya, 2010, published in Zhurnal Prikladnoi Khimii, 2010, Vol. 83, No. 7, pp. 1164–1174.

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Zaitsev, B.A., Shvabskaya, I.D. Mechanism of formation, structure, and properties of heat-resistant network polymers prepared by thermal curing of Rolivsans. Russ J Appl Chem 83, 1270–1280 (2010). https://doi.org/10.1134/S1070427210070190

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  • DOI: https://doi.org/10.1134/S1070427210070190

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