Abstract
Effect of conditions (partial pressure of isoprene, temperature, catalyst concentration, medium) on the rate and selectivity of reactions occurring in interaction of isoprene with water in the presence of orthophosphoric acid as a catalyst was studied at elevated temperatures and pressures in the liquid phase. The reaction orders with respect to isoprene were determined for reactions in which 3-methylbutanone-2,2-methylbutanal, and 2,2-dimethylpropanal are formed. The applicability of various acidity characteristics for describing the rates of the reactions under study are considered.
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Original Russian Text © A.S. Dykman, N.S. Imyanitov, S.A. Polyakov, K.A. Vershinin, 2010, published in Zhurnal Prikladnoi Khimii, 2010, Vol. 83, No. 7, pp. 1153–1158.
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Dykman, A.S., Imyanitov, N.S., Polyakov, S.A. et al. Effect of reaction conditions on the hydration of isoprene. Russ J Appl Chem 83, 1259–1264 (2010). https://doi.org/10.1134/S1070427210070177
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DOI: https://doi.org/10.1134/S1070427210070177