Skip to main content
SpringerLink
Log in

A study of nicotinic acid synthesis on a pilot installation and its simulation

  • Organic Synthesis and Industrial Organic Chemistry
  • Published:
Russian Journal of Applied Chemistry Aims and scope Submit manuscript

Abstract

Technological process parameters of the nicotinic acid synthesis by oxidation of β-picoline on a vanadium-titanium catalyst in a unit tube of a pilot installation were determined: conversion of β-picoline, yield and selectivity for products, and parametric sensitivity of the "hot point" temperature to variation of parameters at the reactor inlet. A mathematical simulation of the process was carried using the model of heat-and-mass transfer in a bed of a tubular reactor and the kinetic model of oxidation of β-picoline.

This is a preview of subscription content, log in via an institution to check access.

Access this article

Log in via an institution

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Institutional subscriptions

Similar content being viewed by others

References

  1. Berezovskii, V.M., Khimiya vitaminov (Chemistry of Vitamins), M.: Nauka, Pishchevaya Prom-st’, 1973.

    Google Scholar 

  2. Chuck, R., Appl. Catal. A: General, 2005, vol. 280. pp. 75–82.

    Article  CAS  Google Scholar 

  3. RF Patent 2371247.

  4. Ovchinnikova, E.V., Andrushkevich, T.V., and Shadrina, L.A., React. Kinet. Catal. Lett., 2004, vol. 82, no. 1, pp. 191–197.

    Article  CAS  Google Scholar 

  5. Ovchinnikova, E.V. and Andrushkevich, T.V., React. Kinet. Catal. Lett., 2008, vol. 93, no. 2, pp. 203–210.

    Article  CAS  Google Scholar 

  6. Bondareva, V.M., Ovchinnikova, E.V., and Andrushkevich, T.V., React. Kinet. Catal. Lett., 2008, vol. 93, no. 2, pp. 327–336.

    Article  Google Scholar 

  7. Popova, G.Ya., Andrushkevich, T.V., Chesalov, Yu.A., and Ovchinnikova, E.V., React. Kinet. Catal. Lett., 2006, vol. 87, no. 2, pp. 387–394.

    Article  CAS  Google Scholar 

  8. Popova, G.Ya., Chesalov, Yu.A., and Andrushkevich, T.V., React. Kinet. Catal. Lett., 2004, vol. 83, no. 2, pp. 353–360.

    Article  CAS  Google Scholar 

  9. Ovchinnikova, E.V., Andrushkevich, T.V., Popova, G.Ya., et al., Chem. Eng. J., 2009, vol. 154, nos. 1-3. pp. 60–68.

    Article  CAS  Google Scholar 

  10. Matros, Yu.Sh., Nestatsionarnye protsessy v kataliticheskikh reaktorakh (Nonsteady rocesses in Catalytic Reactors), Novosibirsk: Nauka, 1982.

    Google Scholar 

  11. Kagyrmanova, A.P., Zolotarskii, I.A., Vernikovskaya, N.V., et al., Teor. Osn. Khim. Tekhnol., 2006, vol. 40, no. 32, pp. 171–183.

    Google Scholar 

Download references

Author information

Authors and Affiliations

  1. Boreskov Institute of Catalysis, Siberian Branch, Russian Academy of Sciences, Novosibirsk, Russia

    E. V. Ovchinnikova, V. A. Chumachenko, N. V. Vernikovskaya, V. N. Kashkin & T. V. Andrushkevich

Authors
  1. E. V. Ovchinnikova
    View author publications

    You can also search for this author in PubMed Google Scholar

  2. V. A. Chumachenko
    View author publications

    You can also search for this author in PubMed Google Scholar

  3. N. V. Vernikovskaya
    View author publications

    You can also search for this author in PubMed Google Scholar

  4. V. N. Kashkin
    View author publications

    You can also search for this author in PubMed Google Scholar

  5. T. V. Andrushkevich
    View author publications

    You can also search for this author in PubMed Google Scholar

Additional information

Original Russian Text © E.V. Ovchinnikova, V.A. Chumachenko, N.V. Vernikovskaya, V.N. Kashkin, T.V. Andrushkevich, 2010, published in Zhurnal Prikladnoi Khimii, 2010, Vol. 83, No. 5, pp. 794–800.

Rights and permissions

Reprints and permissions

About this article

Cite this article

Ovchinnikova, E.V., Chumachenko, V.A., Vernikovskaya, N.V. et al. A study of nicotinic acid synthesis on a pilot installation and its simulation. Russ J Appl Chem 83, 846–853 (2010). https://doi.org/10.1134/S1070427210050162

Download citation

  • Received:

  • Published:

  • Issue Date:

  • DOI: https://doi.org/10.1134/S1070427210050162

Keywords

Search

Navigation