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Synthesis of 1,4,5,6-tetrachloro-7,7-dimethoxybicyclo[2.2.1]hepta-2,5-dienylmethyl esters of p-substituted benzoic acids

  • Organic Synthesis and Industrial Organic Chemistry
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Abstract

The possibility of preparing 1,4,5,6-tetrachloro-7,7-dimethoxybicyclo[2.2.1]hepta-2,5-dienyl-methyl esters of p-substituted benzoic acids by [4+2]cycloaddition of tetrachlorodimethoxycyclo-pentadine to propargyl esters of the corresponding acids was examined. The optimal synthesis conditions were found. The structure of the compounds synthesized was confirmed by independent synthesis and by IR and 1H NMR spectroscopy.

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Authors and Affiliations

  1. Institute of Chemical Problems, National Academy of Sciences of Azerbaijan, Baku, Azerbaijan

    E. G. Mamedbeili, T. G. Kyazimova, S. B. Zeinalov, Kh. I. Gasanov & Z. M. Nagiev

  2. Institute of Petrochemical Processes, National Academy of Sciences of Azerbaijan, Baku, Azerbaijan

    E. G. Mamedbeili, T. G. Kyazimova, S. B. Zeinalov, Kh. I. Gasanov & Z. M. Nagiev

Authors
  1. E. G. Mamedbeili
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  2. T. G. Kyazimova
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  3. S. B. Zeinalov
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  4. Kh. I. Gasanov
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  5. Z. M. Nagiev
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Original Russian Text © E.G. Mamedbeili, T.G. Kyazimova, S.B. Zeinalov, Kh.I. Gasanov, Z.M. Nagiev, 2010, published in Zhurnal Prikladnoi Khimii, 2010, Vol. 83, No. 4, pp. 638–641.

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Mamedbeili, E.G., Kyazimova, T.G., Zeinalov, S.B. et al. Synthesis of 1,4,5,6-tetrachloro-7,7-dimethoxybicyclo[2.2.1]hepta-2,5-dienylmethyl esters of p-substituted benzoic acids. Russ J Appl Chem 83, 691–694 (2010). https://doi.org/10.1134/S107042721004021X

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  • DOI: https://doi.org/10.1134/S107042721004021X

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