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Extraction of copper(II) from weakly acid and ammonia media with N′,N′-dialkylhydrazides of aliphatic carboxylic acids

  • Organic Synthesis and Industrial Organic Chemistry
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Abstract

Dependence of physicochemical properties of N′,N′-dialkylhydrazides of aliphatic carboxylic acids (solubility in kerosene, acid-base properties) on the length of hydrocarbon radicals in the functional group was studied. The extraction capacity for copper(II) salts in weakly acid and ammonia media was examined in the range from pH 5–11 to a NH3 content of 2.7 M. The capacity of the organic phase for copper(II) and re-extraction conditions were determined for the example of N′,N′-dibutylhydrazide of octanoic acid.

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Original Russian Text © T.D. Batueva, A.V. Radushev, V.Yu. Gusev, 2009, published in Zhurnal Prikladnoi Khimii, 2009, Vol. 82, No. 11, pp. 1850–1854.

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Batueva, T.D., Radushev, A.V. & Gusev, V.Y. Extraction of copper(II) from weakly acid and ammonia media with N′,N′-dialkylhydrazides of aliphatic carboxylic acids. Russ J Appl Chem 82, 1997–2001 (2009). https://doi.org/10.1134/S1070427209110172

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  • DOI: https://doi.org/10.1134/S1070427209110172

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