Abstract
Extraction of rhenium(VII) with C7–C10 aliphatic alcohols from HCl and H2SO4 solutions was examined. The rhenium(VII) distribution coefficients were examined in relation to the acidity and temperature. The composition of the extracted complexes and the thermodynamic parameters of extraction were determined. The extraction method of recovery and preconcentration of rhenium(VII) from H2SO4 solutions with secondary octyl alcohol was tested in the counterflow mode.
This is a preview of subscription content, log in via an institution to check access.
Similar content being viewed by others
References
Palant, A.A., Troshkina, I.D., and Chekmarev, A.M., Metallurgiya reniya (Rhenium Metallurgy), Moscow: Nauka, 2007.
Antonov, A.V., Kubasov, V.L., Ishchenko, A.A., et al., Izv. Vyssh. Uchebn. Zaved., Tsvet. Met., 2006, no. 1, pp. 6–12.
Antonov, A.V., Kubasov, V.L., Ishchenko, A.A., et al., Izv. Vyssh Uchebn. Zaved., Tsvet. Met., 2006, no. 2. pp. 21–27.
Sadrnezhaad, S.K. and Alamdari, E.K., Metallurg. Mater. Transact. B, 2001, vol. 32B, February, pp. 5–10.
Gukasyan, Z.G., Barysheva, K.F., Saakyan, O.A., and Arustamyan, R.K., Nauchn. Soobshch. Nauchno-Issled. Proekt. Inst. Tsvet. Met. (Armniprostsvetmet), 1979, no. 21, pp. 16–18.
Gukasyan, Zh.G., Saakyan, O.A., Arustamyan, R.K., Tsvet. Met., 1979, no. 12, pp. 61–62.
Travkin, V.F., Kubasov, V.L., Ishchenko, A.A., et al., Tsvet. Metallurg., 2005, no. 1, pp. 5–10.
Kasikov, A.G. and Petrova, A.M., Zh. Prikl. Khim., 2007, vol. 80, no. 4, pp. 689–690.
Nikolotova, Z.I. and Kartashova, N.A., Spravochnik po ekstraktsii (Handbook on Extraction), Moscow: Atomizdat, 1976.
Rabinovich, V.A. and Khavin, Z.Ya., Kratkii khimicheskii spravochnik (Concise Chemical Handbook), Leningrad: Khimiya, 1977.
Spravochnik khimika: osnovnye svoistva neorganicheskikh i organicheskikh soedinenii (Chemist’s Reference Book: Basic Properties of Inorganic and Organic Compounds), Nikol’skii, B.P., Ed., Leningrad: Khimiya, 1964, Vol. 2.
Wilhoit, R.C. and Zwolinski, B.J., J. Chem. Reference Data, 1973, vol. 2, no. 1, pp. 1–420.
Borisova, L.V. and Ermakov, A.N., Analiticheskaya khimiya reniya (Analytical Chemistry of Rhenium), Moscow: Nauka, 1974.
Zolotov, Yu.A., Ioffa, B.Z., and Chuchalin, L.K., Ekstraktisya galogenidnykh kompleksov metallov (Extraction of Halide Complexes of Metals), Moscow: Nauka, 1973.
Bardin, V.A., Petrov, K.I., and Bol’shakov, K.A., Zh. Neorg, Khim., 1966, vol. 21, no. 9, pp. 2101–2107.
Ivanov, V.G., Gorlenko, V.A., and Geva, O.N., Organicheskaya khimiya (Organic Chemistry), Moscow: Masterstvo, 2003.
Dneprovskii, A.S. and Temnikova, T.I., Teoreticheskie osnovy organicheskoi khimii (Theoretical Fundamentals of Organic Chemistry), Leningrad: Khimiya, 1979.
Zelikman, A.N. and Dragan L., Zh. Neorg. Khim., 1967, vol. 12, pp. 261–268.
Taganov, B.B., Syachinova, N.V., and Slavogorodskaya, N.V., Metody vydeleniy i opredeleniya (ekstraktiya i khromatographiya): Ucheb. Posobie ((Methods of Isolation and Determination: Extraction and Chromatography: Handbook), Ulan-Ude: Vost.-Sib. Gos. Tech. Univ., 2004.
Reznichenko, V.A., Palant, A.A., and Solov’ev, V.I., Kompleksnoe ispol’zovanie syr’ya v tekhnologii tugoplavkikh metallov (Complex Use of Raw Materials in High-Melting Metal Technology), Moscow: Nauka, 1988.
Sklokin, L.I., Tyuremnov, A.V., and Kalinnikov, V.T., Khim. Tekhnol., 2002, no. 8, pp. 25–31.
RF Patent 2330900.
Author information
Authors and Affiliations
Additional information
Original Russian Text © A.G. Kasikov, A.M. Petrova, 2009, published in Zhurnal Prikladnoi Khimii, 2009, Vol. 82, No. 2, pp. 189–195.
Rights and permissions
About this article
Cite this article
Kasikov, A.G., Petrova, A.M. Extraction of rhenium(VII) with aliphatic alcohols from acid solutions. Russ J Appl Chem 82, 197–203 (2009). https://doi.org/10.1134/S1070427209020050
Received:
Published:
Issue Date:
DOI: https://doi.org/10.1134/S1070427209020050