Skip to main content
Log in

Synthesis and physicochemical properties of low-substituted cationic ethers of starch

  • Macromolecular Compounds and Polymeric Materials
  • Published:
Russian Journal of Applied Chemistry Aims and scope Submit manuscript

Abstract

The kinetics of the formation of cationic starch ethers under the action of 3-chloro-2-hydroxypropyltrimethylammonium chloride is studied in relation to the reactant molar ratio, temperature, and concentration of the starch suspension. Comparative data on how the content of the introduced catoinic groups depends on the origin of native starch are presented. The efficiency of starch cationization and the physicochemical properties of the synthesized samples are examined by chemical analysis, scanning electron microscopy, X-ray diffraction analysis, and thermal gravimetric analysis.

This is a preview of subscription content, log in via an institution to check access.

Access this article

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Similar content being viewed by others

References

  1. Solarek, D.B., Modified Starches: Properties and Uses, Wurzburg, O.B., Ed., Boca Raton, Florida: CRC, 1986, pp. 113–129.

    Google Scholar 

  2. Nachtergaele, W., Starch/Starke, 1989, vol. 41, pp. 27–31.

    Article  CAS  Google Scholar 

  3. Radosta, S., Vorwerg, W., Ebert, A., et al., Starch/Starke, 2004, vol. 56, pp. 277–287.

    Article  CAS  Google Scholar 

  4. Xie, F., Yu, L., Liu, H., and Chen, L., Starch/Starke, 2006, vol. 58, pp. 131–139.

    Article  CAS  Google Scholar 

  5. Hellwing, G., Bischoff, D., and Rubo, A., Starch/Starke, 1992, vol. 44, pp. 69–74.

    Article  Google Scholar 

  6. Ruthenberg, M.W. and Solarek, D.B., Starch, Chemistry and Technology, Whistler R.L., BeMiller J.N., and Paschall, E.F., Eds., San Diego, California: Academic, 1984, 2nd ed, pp. 354–364.

    Google Scholar 

  7. Della Valle, G., Colonna, P., and Nantes, J.T., Starch/Starke, 1991, vol. 43, pp. 300–307.

    Article  Google Scholar 

  8. Gimmler, N. and Meuser, F., Starch/Starke, 1994, vol. 46, pp. 268–276.

    Google Scholar 

  9. Manelius, R., Buleon, A., Nurmi, K., and Bertoft, E., Carbohydr. Res., 2000, vol. 329, pp. 621–633.

    Article  CAS  Google Scholar 

  10. Hamunen, A., Starch/Starke, 1995, vol. 47, pp. 215–219.

    Article  CAS  Google Scholar 

  11. Liu, H., Corke, H., and Ramsden, L., J. Agric. Food Chem., 1999, vol. 47, pp. 2523–2528.

    Article  CAS  Google Scholar 

  12. Aggarwal, P. and Dollimore, D., Thermochim. Acta, 1998, vol. 324, pp. 1–8.

    Article  CAS  Google Scholar 

  13. Yook, C., Sosulski, F., and Bhirud, P.R., Starch/Starke, 1994, vol. 46, pp. 393–399.

    Article  CAS  Google Scholar 

  14. Vihervaara, T., Brunn, H.H., Backman, R., and Paakkanen, M., Starch/Starke, 1990, vol. 42, pp. 64–68.

    Article  CAS  Google Scholar 

Download references

Author information

Authors and Affiliations

Authors

Additional information

Original Russian Text © S.M. Butrim, N.S. Butrim, T.D. Bil’dyukevich, T.L. Yurkshtovich, F.N. Kaputskii, 2008, published in Zhurnal Prikladnoi Khimii, 2008, Vol. 81, No. 11, pp. 1911–1917.

Rights and permissions

Reprints and permissions

About this article

Cite this article

Butrim, S.M., Butrim, N.S., Bil’dyukevich, T.D. et al. Synthesis and physicochemical properties of low-substituted cationic ethers of starch. Russ J Appl Chem 81, 2026–2032 (2008). https://doi.org/10.1134/S107042720811030X

Download citation

  • Received:

  • Published:

  • Issue Date:

  • DOI: https://doi.org/10.1134/S107042720811030X

Keywords

Navigation