Skip to main content
Log in

Oxidative bromination of aniline and its derivatives

  • Brief Communication
  • Published:
Russian Journal of Applied Chemistry Aims and scope Submit manuscript

Abstract

Oxidative bromination of aniline and its derivatives containing various substituents (CH3, Cl, NO2, COOH) in ortho, meta, and para positions with a brominating mixture of NaBr (KBr) and 20–22% hydrogen peroxide in 6–8% hydrochloric acid at the molar ratio aniline : NaBr (KBr) : H2O2 : HCl = 1 : 3.5 : 3.2 : 4.5 is described.

This is a preview of subscription content, log in via an institution to check access.

Access this article

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

References

  1. Aseeva, R.M. and Zaikov, G.E., Snizhenie goryuchesti polimernykh materialov (Reducing the Combustibility of Polymeric Materials), Moscow: Znanie, 1981.

    Google Scholar 

  2. Gaevskii, B.D., Dorofeev, V.T., Matveeva, A.P., and Rilo, R.P., Chemistry of 2,4,6-tribromoaniline, VNIIiodobrom, Available from VINITI, Saki, no. 962.

  3. Badische Anilin und Soda Fabrik, Chem. Industrie J., 1954, vol. 72, no. 5, pp. 965–968.

    Google Scholar 

  4. JPN patent 7521.

  5. Golodnikov, G.V., and Mandel’shtam, T.V., Praktikum po organicheskomu sintezu (Practical Course of Organic Synthesis), Ogloblin, K.A., Ed., Leningrad: Len. Gos. Univ., 1976.

    Google Scholar 

  6. FRG Patent Appl. 2 723 137.

  7. Snyder, H.R. and Geller, H.C., J. Amer. Chem. Soc., 1952, vol. 74, p. 2006.

    Article  CAS  Google Scholar 

  8. USSR Inventor’s Certificate, no. 1 398 346.

  9. Akhrem, R.M. and Kuznetsova, A.I., Tonkosloinaya khromatographiya (Thin-Film Chromatography), Moscow: Nauka, 1964.

    Google Scholar 

Download references

Author information

Authors and Affiliations

Authors

Additional information

Original Russian Text © M.S. Salakhov, B.T. Bagmanov, V.S. Umaeva, M.I. Bagmanova, 2008, published in Zhurnal Prikladnoi Khimii, 2008, Vol. 81, No. 8, pp. 1404–1406.

Rights and permissions

Reprints and permissions

About this article

Cite this article

Salakhov, M.S., Bagmanov, B.T., Umaeva, V.S. et al. Oxidative bromination of aniline and its derivatives. Russ J Appl Chem 81, 1479–1481 (2008). https://doi.org/10.1134/S1070427208080314

Download citation

  • Received:

  • Published:

  • Issue Date:

  • DOI: https://doi.org/10.1134/S1070427208080314

Keywords

Navigation