Abstract
Oxidative bromination of aniline and its derivatives containing various substituents (CH3, Cl, NO2, COOH) in ortho, meta, and para positions with a brominating mixture of NaBr (KBr) and 20–22% hydrogen peroxide in 6–8% hydrochloric acid at the molar ratio aniline : NaBr (KBr) : H2O2 : HCl = 1 : 3.5 : 3.2 : 4.5 is described.
References
Aseeva, R.M. and Zaikov, G.E., Snizhenie goryuchesti polimernykh materialov (Reducing the Combustibility of Polymeric Materials), Moscow: Znanie, 1981.
Gaevskii, B.D., Dorofeev, V.T., Matveeva, A.P., and Rilo, R.P., Chemistry of 2,4,6-tribromoaniline, VNIIiodobrom, Available from VINITI, Saki, no. 962.
Badische Anilin und Soda Fabrik, Chem. Industrie J., 1954, vol. 72, no. 5, pp. 965–968.
JPN patent 7521.
Golodnikov, G.V., and Mandel’shtam, T.V., Praktikum po organicheskomu sintezu (Practical Course of Organic Synthesis), Ogloblin, K.A., Ed., Leningrad: Len. Gos. Univ., 1976.
FRG Patent Appl. 2 723 137.
Snyder, H.R. and Geller, H.C., J. Amer. Chem. Soc., 1952, vol. 74, p. 2006.
USSR Inventor’s Certificate, no. 1 398 346.
Akhrem, R.M. and Kuznetsova, A.I., Tonkosloinaya khromatographiya (Thin-Film Chromatography), Moscow: Nauka, 1964.
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Original Russian Text © M.S. Salakhov, B.T. Bagmanov, V.S. Umaeva, M.I. Bagmanova, 2008, published in Zhurnal Prikladnoi Khimii, 2008, Vol. 81, No. 8, pp. 1404–1406.
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Salakhov, M.S., Bagmanov, B.T., Umaeva, V.S. et al. Oxidative bromination of aniline and its derivatives. Russ J Appl Chem 81, 1479–1481 (2008). https://doi.org/10.1134/S1070427208080314
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DOI: https://doi.org/10.1134/S1070427208080314