Skip to main content
Log in

Solubility in the system constituted by acetic acid, n-propanol, water, and n-propyl acetate

  • Physicochemical Studies of Systems and Processes
  • Published:
Russian Journal of Applied Chemistry Aims and scope Submit manuscript

Abstract

Experimental data on the solubility in the system constituted by acetic acid, n-propanol, water, and n-propyl acetate at 313.15 K are presented. The position of the critical curve for the liquid-liquid equilibrium, including that of the critical points on the chemical equilibrium surface, is discussed.

This is a preview of subscription content, log in via an institution to check access.

Access this article

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Similar content being viewed by others

References

  1. Serafimov, L.A. and Balashov, M.I., Massoperedacha s khimicheskoi reaktsiei (Mass Transfer Involving a Chemical Reaction), Leningrad: Khimiya, 1971, chapter 17, p. 186.

    Google Scholar 

  2. Pisarenko, Yu.A., Kardona, K.A., and Serafimov, L.A., Reaktsionno-rektifikatsionnye protsessy: dostizheniya v oblasti issledovaniya i prakticheskogo ispol’zovaniya (Reactive-Rectification Processes: Advances in Research and Practical Application), Moscow: Luch, 2001.

    Google Scholar 

  3. Serafimov, L.A., Pisarenko, Yu.A., and Kulov, N.N., Chem. Eng. Sci., 1999, vol. 54, pp. 1383–1388.

    Article  CAS  Google Scholar 

  4. Doherty, M.F. and Malone, M.F., Conceptual Design of Distillation Systems, New York: McGraw-Hill, 2001.

    Google Scholar 

  5. Reactive Distillation: Status and Future Directions, Sundmacher, K. and Kienle, A., EDs., Weinheim: WILEYVCH Verlag GmbH & Co. KGaA, 2003.

    Google Scholar 

  6. Zharov, V.T., Voprosy termodinamiki geterogennykh sistem i poverkhnostnykh yavlenii (Problems of Thermodynamics of Heterogeneous Systems and Surface Phenomena), Storonkin, A.V., Ed., Leningrad: Len. Gos. Univ., 1973, issue 2, pp. 35–53.

    Google Scholar 

  7. Pervukhin, O.K. and Zharov, V.T., Voprosy termodinamiki geterogennykh sistem i teorii poverkhnostnykh yavlenii (Problems of Thermodynamics of Heterogeneous Systems and Surface Phenomena), Leningrad: Len. Gos. Univ., 1979, issue 5, pp. 3–29.

    Google Scholar 

  8. Barbosa, D. and Doherty, M.F., Chem. Eng. Sci., 1988, vol. 43, no. 3, pp. 529–540.

    Article  CAS  Google Scholar 

  9. Taylor, R. and Krishna, R., Chem. Eng. Sci., 2000, vol. 55, pp. 5183–5229.

    Article  CAS  Google Scholar 

  10. Sokolov, V.A. and Markuzin, N.P., Eksperimental’nyedannye o ravnovesii mezhdu zhidkost’yu i parom i o khimicheskoi reaktsii v sisteme uksusnaya kislota-propilovyi spirt-voda-propilatsetat (Experimental Data on the Liquid-Vapor Equilibrium and on the Chemical Reaction in the System Constituted by Acetic Acid, n-Propanol, Water, and n-Propyl Acetate), Available from VINITI, 1982, Leningrad, no. 35–82.

  11. Toikka, A.M., Gorban’, Yu.P., Ivanova, Zh.V., and Kocherbitov, V.V., Zh. Prikl. Khim., 1997, vol. 70, no. 1, pp. 44–46.

    CAS  Google Scholar 

  12. Smirnova, N.A., Morachevskii, A.G., and Storonkin, A.V., Vestn. Len. Gos. Univ., 1959, no. 22, pp. 70–76.

  13. Smirnova, N.A., Morachevskii, A.G., and Storonkin, A.V., Vestn. Len. Gos. Univ., 1963, no. 22, pp. 97–104.

  14. Kocherbitov, V.V. and Toikka, A.M., Zh. Prikl. Khim., 1999, vol. 72, no. 10, pp. 1615–1617.

    CAS  Google Scholar 

  15. Kocherbitov, V.V., Thermodynamic Stability and Phase Equilibrium in the system Constituted by Acetic Acid, n-Propanol, Water, and n-Propyl Acetate, Cand. Sci. Dissertation, St. Petersburg, 1997.

  16. Toikka, M., Distillation & Absorption 2006, Sorensen, E., Ed., Rugby, UK: IChemE, 2006, pp. 563–573.

    Google Scholar 

  17. Spravochnik khimika (Chemist’s Handbook), Nikol’skii, B.P., Ed., Leningrad: GNTIKhL, 1963.

    Google Scholar 

  18. Khimicheskaya entsiklopediya v 5-ti tomakh (Chemical Encyclopedia in 5 vols.), Knunyants, L.I., Chief Ed., Moscow: Sovetskaya Entsiklopediya-Bol’shaya Rossiiskaya Entsiklopediya, 1988–1998.

    Google Scholar 

  19. Letcher, T.M., Wooten, S., Shuttleworth, B., and Heward, C., J. Chem. Thermodyn., 1986, vol. 18, pp. 1037–1042.

    Article  CAS  Google Scholar 

  20. Letcher, T.M. and Siswana, P.M., Fluid Phase Equilib., 1992, vol. 74, pp. 203–217.

    Article  CAS  Google Scholar 

  21. Novak, J.P., Matous, J., and Pick, J., Liquid-Liquid Equilibrium, Prague: Academia, 1987.

    Google Scholar 

  22. Toikka, A.M. and Jenkins, J.D., Chem. Eng. J., 2002, vol. 89, pp. 1–27.

    Article  CAS  Google Scholar 

  23. Zharov, V.T., Zh. Fiz. Khim., 1970, vol. 44, pp. 1967–1974.

    CAS  Google Scholar 

  24. Kocherbitov, V.V. and Toikka, A.M., Vestn. SPb. Gos. Univ., Ser. 4, Fiz., Khim., 1998, issue 3(no. 18), pp. 120–124.

    Google Scholar 

  25. Furzer, I.A., Chem. Eng. Sci., 1994, vol. 49, pp. 2544–2549.

    Article  CAS  Google Scholar 

  26. Wasylkiewicz, S.K. and Ung, S., Fluid Phase Equilib., 2000, vol. 175, pp. 253–272.

    Article  CAS  Google Scholar 

  27. Qi, Z., Kolah, A., and Sundmacher, K., Chem. Eng. Sci., 2002, vol. 57, pp. 163–178

    Article  CAS  Google Scholar 

  28. Qi, Z. and Sundmacher, K., Comp. Chem. Eng., 2002, vol. 26, pp. 1459–1471.

    Article  CAS  Google Scholar 

Download references

Author information

Authors and Affiliations

Authors

Additional information

Original Russian Text © M.A. Toikka, B.I. Gorovits, A.M. Toikka, 2008, published in Zhurnal Prikladnoi Khimii, 2008, Vol. 81, No. 2, pp. 234–240.

Rights and permissions

Reprints and permissions

About this article

Cite this article

Toikka, M.A., Gorovits, B.I. & Toikka, A.M. Solubility in the system constituted by acetic acid, n-propanol, water, and n-propyl acetate. Russ J Appl Chem 81, 223–230 (2008). https://doi.org/10.1134/S1070427208020122

Download citation

  • Received:

  • Published:

  • Issue Date:

  • DOI: https://doi.org/10.1134/S1070427208020122

Keywords

Navigation