Skip to main content
SpringerLink
Log in

Kinetics and mechanism of the processes occurring at graphite anode in a CaO-CaCl2 melt

  • Applied Electrochemistry and Corrosion Protection of Metals
  • Published:
Russian Journal of Applied Chemistry Aims and scope Submit manuscript

Abstract

The polarization of a graphite anode in a CaCl2-CaO melt in the temperature range 790–870°C at CaO concentrations of 1–8 mol % and current densities of 10−2–10 A cm−2 was studied. The temperature and concentration dependences of the limiting current spent for the oxidation of oxygen ions were determined.

This is a preview of subscription content, log in via an institution to check access.

Access this article

Log in via an institution

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Institutional subscriptions

Similar content being viewed by others

References

  1. Abiko, T., Park, I., and Okabe, T.H., Abstracts of Papers, The 10th World Conf. on Titanium, Hamburg (Germany), July 15, 2003.

  2. Wicks, C.E., and Block, F.E., Thermodynamic Properties of 65 Elements, Their Oxides, Halides, Carbides, and Nitrides, Washington: US Government, 1963.

    Google Scholar 

  3. Antipin, L.N., and Khudyakov, A.N., Zh. Prikl. Khim., 1956, vol. 29, no. 6, pp. 908–914.

    CAS  Google Scholar 

  4. Ono, K., and Suzuki, R.O., J. Met., 2002, February, pp. 59–61.

  5. Baimakov, Yu.V., and Vetyukov, M.M., Elektroliz rasplavlennykh solei (Electrolysis of Molten Salts), Leningrad: Metallurgiya, 1966.

    Google Scholar 

  6. Ivanovskii, L.E., Lebedev, V.A., and Nekrasov, V.N., Anodnye protsessy v rasplavlennykh galogenidakh (Anode Processes in Molten Halides), Moscow: Nauka, 1983, pp. 58–72.

    Google Scholar 

Download references

Author information

Authors and Affiliations

  1. State Educational Institution for Higher Professional Education, Ural State Technical University, Yekaterinburg, Russia

    V. A. Lebedev, V. I. Sal’nikov, M. V. Tarabaev, I. A. Sizikov & D. A. Rymkevich

  2. AVISMA Titanium and Magnesium Combine, Open Joint-Stock Company, Berezniki, Perm krai, Russia

    V. A. Lebedev, V. I. Sal’nikov, M. V. Tarabaev, I. A. Sizikov & D. A. Rymkevich

Authors
  1. V. A. Lebedev
    View author publications

    You can also search for this author in PubMed Google Scholar

  2. V. I. Sal’nikov
    View author publications

    You can also search for this author in PubMed Google Scholar

  3. M. V. Tarabaev
    View author publications

    You can also search for this author in PubMed Google Scholar

  4. I. A. Sizikov
    View author publications

    You can also search for this author in PubMed Google Scholar

  5. D. A. Rymkevich
    View author publications

    You can also search for this author in PubMed Google Scholar

Additional information

Original Russian Text © V.A. Lebedev, V.I. Sal’nikov, M.V. Tarabaev, I.A. Sizikov, D.A. Rymkevich, 2007, published in Zhurnal Prikladnoi Khimii, 2007, Vol. 80, No. 9, pp. 1462–1466.

Rights and permissions

Reprints and permissions

About this article

Cite this article

Lebedev, V.A., Sal’nikov, V.I., Tarabaev, M.V. et al. Kinetics and mechanism of the processes occurring at graphite anode in a CaO-CaCl2 melt. Russ J Appl Chem 80, 1498–1502 (2007). https://doi.org/10.1134/S107042720709011X

Download citation

  • Received:

  • Accepted:

  • Issue Date:

  • DOI: https://doi.org/10.1134/S107042720709011X

Keywords

Search

Navigation