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Properties of nitric acid palladium solutions with a high metal concentration

  • Inorganic Synthesis and Industrial Inorganic Chemistry
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Abstract

Nitric acid solutions (c Pd up to 3.2 M) with variable HNO3 concentration were studied by electronic spectroscopy, 14N and 17O NMR, acid-base titration, gravimetry, and other methods. Solid phases that precipitated on storing these solutions were studied by X-ray phase analysis, thermogravimetry, and IR spectroscopy. The conditions for stability of particular Pd(II) species were determined, and specific features of aging of such highly concentrated palladium solutions were revealed. A procedure for palladium isolation as [Pd(NH3)4](NO3)2 from nitric acid solutions in 98% yield was developed.

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Authors and Affiliations

  1. Nikolaev Institute of Inorganic Chemistry, Siberian Division, Russian Academy of Sciences, Novosibirsk, Russia

    A. B. Venediktov, S. V. Korenev, S. P. Khranenko, S. V. Tkachev, P. E. Plyusnin, S. N. Mamonov, L. V. Ivanova & V. A. Vostrikov

  2. Gulidov Krasnoyarsk Factory of Nonferrous Metals, Open Joint-Stock Company, Krasnoyarsk, Russia

    A. B. Venediktov, S. V. Korenev, S. P. Khranenko, S. V. Tkachev, P. E. Plyusnin, S. N. Mamonov, L. V. Ivanova & V. A. Vostrikov

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  1. A. B. Venediktov
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  2. S. V. Korenev
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  3. S. P. Khranenko
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  4. S. V. Tkachev
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  5. P. E. Plyusnin
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  6. S. N. Mamonov
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  7. L. V. Ivanova
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  8. V. A. Vostrikov
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Additional information

Original Russian Text © A.B. Venediktov, S.V. Korenev, S.P. Khranenko, S.V. Tkachev, P.E. Plyusnin, S.N. Mamonov, L.V. Ivanova, V.A. Vostrikov, 2007. published in Zhurnal Prikladnoi Khimii, 2007, Vol. 80, No. 5, pp. 716–725.

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Venediktov, A.B., Korenev, S.V., Khranenko, S.P. et al. Properties of nitric acid palladium solutions with a high metal concentration. Russ J Appl Chem 80, 695–704 (2007). https://doi.org/10.1134/S1070427207050023

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  • DOI: https://doi.org/10.1134/S1070427207050023

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