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Functionalized silicon-containing imino enols and enamino ketones prepared by hydrolytic condensation

  • Macromolecular Chemistry and Polymeric Materials
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Abstract

A mixture of two isomers of organosilicon carbofunctional compounds, 4-(3′-triethoxysilylpropylimino)pent-2-en-2-ol (EtO)3Si-CH2CH2CH2-N=C(Me)-CH=C(Me)-OH (Ia, 83%) and 4-(3′-triethoxysilylpropylamino)pent-3-en-2-one (EtO)3-CH2CH2CH2-NH-C(Me)=CH-C(O)Me (Ib, 17%) was prepared by reaction of 3-aminopropyltriethoxysilane with acetylacetone. The use of trimethylsilyl ether of acetylacetone instead of acetylacetone yields Ia (84%) and silylated derivatives (Me3SiO)n(EtO)3−n Si-CH2CH2CH2-N=C(Me)CH=C(Me)OH (II) (16%). Solid, liquid, or resinous products were prepared by hydrolytic condensation of I and II. Compositions for preparing transparent sol-gel films were developed.

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Authors and Affiliations

  1. Razuvaev Institute of Organometallic Chemistry, Russian Academy of Sciences, Nizhni Novgorod, Russia

    V. V. Semenov, N. V. Melenskova, N. F. Cherepennikova, Yu. A. Kurskii, O. V. Kuznetsova & M. A. Lopatin

  2. Lovachevsky State University, Nizhni Novgorod, Russia

    V. V. Semenov, N. V. Melenskova, N. F. Cherepennikova, Yu. A. Kurskii, O. V. Kuznetsova & M. A. Lopatin

Authors
  1. V. V. Semenov
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  2. N. V. Melenskova
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  3. N. F. Cherepennikova
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  4. Yu. A. Kurskii
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  5. O. V. Kuznetsova
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  6. M. A. Lopatin
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Original Russian Text © V.V. Semenov, N.V. Melenskova, N.F. Cherepennikova, Yu.A. Kurskii, O.V. Kuznetsova, M.A. Lopatin, 2007, published in Zhurnal Prikladnoi Khimii, 2007, Vol. 80, No. 4, pp. 663–669.

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Semenov, V.V., Melenskova, N.V., Cherepennikova, N.F. et al. Functionalized silicon-containing imino enols and enamino ketones prepared by hydrolytic condensation. Russ J Appl Chem 80, 647–653 (2007). https://doi.org/10.1134/S107042720704026X

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  • DOI: https://doi.org/10.1134/S107042720704026X

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