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Synthesis of heteroaromatic carboxylic acids by carbonylation of hetaryl halides with catalysts based on cobalt carbonyl modified with epoxides

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Abstract

A new method for the synthesis of heteroaromatic acids and their derivatives (esters and salts) by carbonylation of the corresponding halides was developed. Hetaryl halides were activated in alcoholic-alkali medium by highly active catalytic systems based on cobalt carbonyl modified with epoxides, developed previously for carbonylation of aryl halides.

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Authors and Affiliations

  1. VNIIneftekhim Open Joint-Stock Company, St. Petersburg, Russia

    V. P. Boyarskii, T. E. Zhesko, E. V. Larionov & V. A. Polukeev

  2. NPF Gallar Limited Liability Company, St. Petersburg, Russia

    V. P. Boyarskii, T. E. Zhesko, E. V. Larionov & V. A. Polukeev

  3. St. Petersburg State University, St. Petersburg, Russia

    V. P. Boyarskii, T. E. Zhesko, E. V. Larionov & V. A. Polukeev

  4. Vekton Private Company, St. Petersburg, Russia

    V. P. Boyarskii, T. E. Zhesko, E. V. Larionov & V. A. Polukeev

Authors
  1. V. P. Boyarskii
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  2. T. E. Zhesko
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  3. E. V. Larionov
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  4. V. A. Polukeev
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Additional information

Original Russian Text © V.P. Boyarskii, T.E. Zhesko, E.V. Larionov, V.A. Polukeev, 2007, published in Zhurnal Prikladnoi Khimii, 2007, Vol. 80, No. 4, pp. 584–589.

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Boyarskii, V.P., Zhesko, T.E., Larionov, E.V. et al. Synthesis of heteroaromatic carboxylic acids by carbonylation of hetaryl halides with catalysts based on cobalt carbonyl modified with epoxides. Russ J Appl Chem 80, 571–575 (2007). https://doi.org/10.1134/S1070427207040106

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  • DOI: https://doi.org/10.1134/S1070427207040106

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