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Promising prospects for using partially fluorinated alcohols as O-nucleophilic reagents in organofluoric synthesis

  • Organic Synthesis and Industrial Organic Chemistry
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Abstract

Perfluoroolefins react with isopropyl alcohol under the conditions of radical initiation to form partially fluorinated aliphatic alcohols. The reactions of these alcohols with hexafluoropropylene and compounds containing labile halogen atoms (in particular, with allyl bromide and epichlorohydrin) were studied.

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Original Russian Text © A.A. Il’in, A.N. Il’in, Yu.L. Bakhmutov, G.G. Furin, L.M. Pokrovskii, 2007, published in Zhurnal Prikladnoi Khimii, 2007, Vol. 80, No. 3, pp. 405–420.

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Il’in, A.A., Il’in, A.N., Bakhmutov, Y.L. et al. Promising prospects for using partially fluorinated alcohols as O-nucleophilic reagents in organofluoric synthesis. Russ J Appl Chem 80, 405–418 (2007). https://doi.org/10.1134/S1070427207030123

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  • DOI: https://doi.org/10.1134/S1070427207030123

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