Abstract
The conditions of complexation of 1,2-diacylhydrazines (H2L) C6H5C(O)NHNHC(O)R, where R = C6H5 or CH3, with Cu(II) ions in alkaline solutions were studied. The composition of the complexes formed by precipitation of Cu(II) from alkaline solutions, (CuOH)2L and CuL, was determined. The possibility of afterpurification of solutions with a low Cu(II) content by pneumatic flotation using H2L was examined.
Similar content being viewed by others
References
Radushev, A.V., Zubareva, G.I., and Chekanova, L.G., Izv. Vyssh. Uchebn. Zaved., Tsvetn. Metall., 1999, no. 1, pp. 3–6.
Chekanova, L.G., Radushev, A.V., and Shabalina, L.S., in Khimiya i tekhnologiya ekstraktsii: Sbornik nauchnykh trudov (Chemistry and Technology of Extraction: Coll. of Scientific Works), Moscow: Ross. Khimiko-Tekhnol. Univ. im. D.I. Mendeleeva, 2001, vol. 2, pp. 111–115.
Chekanova, L.G., Radushev, A.V., El’chishcheva, Yu.B., and Kazakova, Yu.V., Zh. Prikl. Khim., 2004, vol. 77, no. 7, pp. 1090–1093.
Drozdetskii, A.G., Radushev, A.V., Turbin, A.S., et al., Zh. Prikl. Khim., 1998, vol. 71, no. 2, pp. 288–293.
Radushev, A.V., Chekanova, L.G., Gusev, V.Yu., and Sazonova, E.A., Zh. Anal. Khim., 2000, vol. 55, no. 5, pp. 496–499.
Podchainova, V.N. and Simonova, L.N., Analiticheskaya khimiya elementov: Med’ (Analytical Chemistry of Elements: Copper), Moscow: Nauka, 1990.
Chekanova, L.G., Radushev, A.V., Lesnov, A.E., and Sazonova, E.A., Zh. Obshch. Khim., 2002, vol. 72, no. 8, pp. 1315–1319.
Machkhoshvili, R.I., Coordination Compounds of Metals with Hydrazines, Doctoral Dissertation, Moscow, 1983.
Chekanova, L.G., Radushev, A.V., Shabalina, L.S., and Tiunova, T.G., Izv. Vyssh. Uchebn. Zaved., Tsvetn. Metall., 2004, no. 5, pp. 23–26.
Lur’e, Yu.Yu., Spravochnik po analiticheskoi khimii (Handbook of Analytical Chemistry), Moscow: Khimiya, 1979.
Teterina, N.N., Adeev, S.M., Zubareva, G.I., and Radushev, A.V., Izv. Vyssh. Uchebn. Zaved., Tsvetn. Metall., 1997, no. 3, pp. 6–9.
Pravila okhrany poverkhnostnykh vod ot zagryazneniya stochnymi vodami (Regulations on Protection of Surface Waters from Pollution by Wastewater), Moscow: Ministerstvo Melioratsii i Vodnogo Khozyaistva SSSR, 1975.
Author information
Authors and Affiliations
Additional information
Original Russian Text © A.V. Radushev, L.G. Chekanova, Yu.B. El’chishcheva, A.V. Ershova, 2007, published in Zhurnal Prikladnoi Khimii, 2007, Vol. 80, No. 3, pp. 370–373.
Rights and permissions
About this article
Cite this article
Radushev, A.V., Chekanova, L.G., El’chishcheva, Y.B. et al. 1,2-Dibenzoyl- and 1-benzoyl-2-acetylhydrazines as reagents for recovering Cu(II) ions from alkaline solutions. Russ J Appl Chem 80, 368–371 (2007). https://doi.org/10.1134/S1070427207030056
Received:
Accepted:
Issue Date:
DOI: https://doi.org/10.1134/S1070427207030056