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Bisacylated diethylenetriamines as extractants for nonferrous metals from hydrochloric acid solutions

  • Organic Synthesis and Industrial Organic Chemistry
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Abstract

A series of bisacylated polyethylenepolyamines with linear and α-and α,α′-branched substituents were synthesized. The effects of the number of the nitrogen atoms in the polyethylenepolyamine fragment of the reagent and of the length and branching of its alkyl radicals on the extractant distribution between the organic and aqueous phases was studied. The performance characteristics of the extractants, such as the loss with the aqueous phase, hydrolytic stability, back extraction conditions for nonferrous metals, and Zn(II)/Fe(III) and Zn(II)/Cu(II) partition coefficients, were examined.

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References

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Authors and Affiliations

  1. Institute of Organic Chemistry, Ufa Scientific Center, Russian Academy of Sciences, Ufa, Bashkortostan, Russia

    S. O. Bondareva, Yu. I. Murinov & V. V. Lisitskii

  2. Bashkir State University, Ufa, Bashkortostan, Russia

    S. O. Bondareva, Yu. I. Murinov & V. V. Lisitskii

Authors
  1. S. O. Bondareva
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  2. Yu. I. Murinov
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  3. V. V. Lisitskii
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Additional information

Original Russian Text © S.O. Bondareva, Yu.I. Murinov, V.V. Lisitskii, 2007, published in Zhurnal Prikladnoi Khimii, 2007, Vol. 80, No. 2, pp. 280–285.

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Bondareva, S.O., Murinov, Y.I. & Lisitskii, V.V. Bisacylated diethylenetriamines as extractants for nonferrous metals from hydrochloric acid solutions. Russ J Appl Chem 80, 279–284 (2007). https://doi.org/10.1134/S107042720702022X

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  • DOI: https://doi.org/10.1134/S107042720702022X

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