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High-efficiency catalysts for norbornene polymerization, based on palladium carboxylates and boron trifluoride

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Abstract

Catalytic systems based on palladium carboxylates and boron trifluoride etherate were studied in the reaction of additive polymerization of nonbornene. The system Pd(OAc)2 + 25BF3OEt2 exhibits a high activity, up to 154 100 kg of nonbornene per mole of Pd per hour.

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Authors and Affiliations

  1. Irkutsk State University, Irkutsk, Russia

    G. Myagmarsuren, V. S. Tkach, D. S. Suslov & F. K. Shmidt

  2. Monogolian National University, Ulan-Bator, Mongolia

    G. Myagmarsuren, V. S. Tkach, D. S. Suslov & F. K. Shmidt

Authors
  1. G. Myagmarsuren
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  2. V. S. Tkach
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  3. D. S. Suslov
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  4. F. K. Shmidt
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Additional information

Original Russian Text © G. Myagmarsuren, V.S. Tkach, D.S. Suslov, F.K. Shmidt, 2007, published in Zhurnal Prikladnoi Khimii, 2007, Vol. 80, No. 2, pp. 253–257.

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Myagmarsuren, G., Tkach, V.S., Suslov, D.S. et al. High-efficiency catalysts for norbornene polymerization, based on palladium carboxylates and boron trifluoride. Russ J Appl Chem 80, 252–256 (2007). https://doi.org/10.1134/S1070427207020164

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  • DOI: https://doi.org/10.1134/S1070427207020164

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