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Temperature dependence of the diffusion coefficient of copper(II) chloride in porous-glass membranes

  • Physicochemical Studies of Systems and Processes
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Abstract

Diffusion transport of a 0.5 M aqueous solution of CuCl2 was studied in a set of porous-glass membranes with predominant pore radii of 4.5 to 70 nm in the temperature range 25–70°C. Raising the temperature causes a rise in diffusion coefficients and their gradual equalization, which eliminates their dimension dependence on the radius of membrane channels.

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References

  1. Churaev, N.V., Fizikokhimiya protsessov massoperenosa v poristykh sredakh (Physical Chemistry of Mass Transfer in Porous Media), Moscow: Khimiya, 1990.

    Google Scholar 

  2. Nikolaev, N.I., Diffuziya v membranakh (Diffusion in Membranes), Moscow: Khimiya, 1980.

    Google Scholar 

  3. Mazurin, O.V., Roskova, G.P., Aver’yanov, V.N., and Antropova, T.V., Dvukhfaznye stekla: struktura, svoistva, primenenie (Two-Phase Glasses: Structure, Properties, and Application), Leningrad: Nauka, 1991.

    Google Scholar 

  4. Roskova, G.P. and Tsekhomskaya, T.S., Fiz. Khim. Stekla, 1981, vol. 7, no. 5, pp. 513–534.

    CAS  Google Scholar 

  5. Burkat, T.M. and Dobychin, D.P., Fiz. Khim. Stekla, 1981, vol. 18, no. 5, pp. 129–140.

    Google Scholar 

  6. Pak, V.N., Nepomnyashchii, A.B., Burkat, T.M., and Kun, Sh.R., Zh. Fiz. Khim., 2005, vol. 79, no. 9, pp. 1411–1414.

    CAS  Google Scholar 

  7. Pak, V.N., Stromova, E.S., Lobov, B.I., and Levkin, A.N., Zh. Prikl. Khim., 2006, vol. 79, no. 3, pp. 363–366.

    Google Scholar 

  8. Pak, V.N., Nepomnyashchii, A.B., and Burkat, T.M., Zh. Fiz. Khim., 2003, vol. 77, no. 11, pp. 1979–1982.

    CAS  Google Scholar 

  9. Pak, V.N., Nepomnyashchii, A.B., Burkat, T.M., and Mal’kova, S.V., Zh. Prikl. Khim., 2002, vol. 75, no. 12, pp. 1959–1962.

    Google Scholar 

  10. Voloshina, O.S., Burkat, T.M., and Pak, V.N., Zh. Fiz. Khim., 2000, vol. 74, no. 6, pp. 1099–1102.

    CAS  Google Scholar 

  11. Takahashi, R., Sodesava, T., and Nishida, H., Phys. Chem. Chem. Phys., 2002, vol. 4, no. 12, pp. 3800–3805.

    Article  CAS  Google Scholar 

  12. Takahashi, R., Sato, S., Sodesava, T., and Katotae, Y., Phys. Chem. Chem. Phys., 2000, vol. 2, no. 4, pp. 1199–1204.

    Article  CAS  Google Scholar 

  13. Antropova, T.V., Tsyganova, T.A., and Krylova, N.L., Fiz. Khim. Stekla, 1990, vol. 16, no. 5, pp. 732–737.

    CAS  Google Scholar 

  14. Mazurin, O.V. and Antropova, T.V., Fiz. Khim. Stekla, 1986, vol. 12, no. 4, pp. 507–510.

    CAS  Google Scholar 

  15. Pak, V.N., Tikhomirova, I.Yu., Burkat, T.M., and Lobov, B.I., Zh. Fiz. Khim., 1999, vol. 93, no. 11, pp. 2024–2028.

    Google Scholar 

  16. Chyraev, N.V., Adv. Coll. Interface Sci., 2003, vol. 104, no. 1, pp. 15–21.

    Google Scholar 

  17. Derjaguin, B.V. and Churaev, N.V., Langmuir, 1987, vol. 3, no. 2, pp. 607–612.

    Article  Google Scholar 

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Original Russian Text © V.N. Pak, E.S. Stromova, 2007, published in Zhurnal Prikladnoi Khimii, 2007, Vol. 80, No. 2, pp. 221–225.

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Pak, V.N., Stromova, E.S. Temperature dependence of the diffusion coefficient of copper(II) chloride in porous-glass membranes. Russ J Appl Chem 80, 221–225 (2007). https://doi.org/10.1134/S1070427207020103

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  • DOI: https://doi.org/10.1134/S1070427207020103

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