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Thermodynamic properties of ternary systems: Calculation of standard enthalpies of solvation of triols, diols, and a series of their ethers in water-methanol mixed solvent

  • Physicochemical Studies of Systems and Processes
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Abstract

An equation for the standard enthalpy of solvation of a compound in a binary solvent is derived. The enthalpies of solvation in water-methanol mixtures are estimated for 1,3-propane-and 1,6-hexanediols, 1,2,4-butane-and 1,3,5-pentanetriols, 2-methoxy-and 2-propoxyethanols, and diethylene glycol. The enthalpy of solvation of 1,2-dimethoxyethane in the water-methanol mixed solvent is determined experimentally.

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Authors and Affiliations

  1. Institute of Chemistry of Solutions, Russian Academy of Sciences, Ivanovo, Russia

    V. P. Korolev

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  1. V. P. Korolev
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Original Russian Text © V.P. Korolev, 2006, published in Zhurnal Prikladnoi Khimii, 2006, Vol. 79, No. 11, pp. 1799–1804.

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Korolev, V.P. Thermodynamic properties of ternary systems: Calculation of standard enthalpies of solvation of triols, diols, and a series of their ethers in water-methanol mixed solvent. Russ J Appl Chem 79, 1779–1784 (2006). https://doi.org/10.1134/S1070427206110085

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  • DOI: https://doi.org/10.1134/S1070427206110085

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