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Mixed phosphates K2MIIIMV(OPO4)2: Heterovalence-substituted analogs of KTiOPO4

  • Inorganic Synthesis and Industrial Inorganic Chemistry
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Abstract

A series of heterovalence-substituted analogs of KTiOPO4 of the general composition K2MIIIMV(OPO4)2 (MIII = Cr, Fe, In; MV = Nb, Ta) were synthesized by crystallization from melts and by solid-phase reactions. Influence of the nature of tri-and pentavalent metals on the conditions of preparation and on the features of phase formation of substituted mixed phosphates was examined. The compounds obtained were characterized by X-ray diffraction analysis and by diffuse reflection spectroscopy.

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Authors and Affiliations

  1. Shevchenko Kiev National University, Kiev, Ukraine

    I. V. Zatovskii, A. A. Babarik & N. S. Slobodyanik

Authors
  1. I. V. Zatovskii
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  2. A. A. Babarik
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  3. N. S. Slobodyanik
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Original Russian Text © I.V. Zatovskii, A.A. Babarik, N.S. Slobodyanik, 2006, published in Zhurnal Prikladnoi Khimii, 2006, Vol. 79, No. 11, pp. 1785–1788.

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Zatovskii, I.V., Babarik, A.A. & Slobodyanik, N.S. Mixed phosphates K2MIIIMV(OPO4)2: Heterovalence-substituted analogs of KTiOPO4 . Russ J Appl Chem 79, 1765–1768 (2006). https://doi.org/10.1134/S107042720611005X

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  • DOI: https://doi.org/10.1134/S107042720611005X

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