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Asymmetric Diels-Alder reaction between acrylates and cyclopentadiene in the presence of chiral catalysts

  • Organic Synthesis and Industrial Organic Chemistry
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Abstract

Asymmetric Diels-Alder reaction between cyclopentadiene and alkyl and cycloalkyl acrylates in the presence of new chiral catalysts, BBr3·MentOEt, AlCl2OMent, BBr2OMent, and BBr(OMent)2, was studied. Optically active bicyclo[2.2.1]hept-2-ene-5-carboxylates were synthesized. The influence of the reaction conditions on the total and optical yields and on the stereoselectivity of the adducts synthesized was examined.

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Authors and Affiliations

  1. Institute of Petrochemical Processes, National Academy of Sciences of Azerbaijan, Baku, Azerbaijan

    E. G. Mamedov

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  1. E. G. Mamedov
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Original Russian Text © E.G. Mamedov, 2006, published in Zhurnal Prikladnoi Khimii, 2006, Vol. 79, No. 10, pp. 1642–1646.

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Mamedov, E.G. Asymmetric Diels-Alder reaction between acrylates and cyclopentadiene in the presence of chiral catalysts. Russ J Appl Chem 79, 1621–1625 (2006). https://doi.org/10.1134/S1070427206100120

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  • DOI: https://doi.org/10.1134/S1070427206100120

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