Abstract
The initiation of free radicals and oxidizability of soap chips were studied by the methods of inhibited and initiated oxidation. A scheme accounting for the effect of phenolic inhibitors (with Ionol and 2-ethylhexyl gallate as examples) was suggested. The kinetic parameters of the main reactions determining the inhibiting activity of these additives were found.
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References
Yasnitskii, B.G. and Korobeinikova, I.E., Antioksidanty v farmatsevticheskoi i pishchevoi promyshlennosti: Obzornaya informatsiya (Antioxidants in Pharmaceutical and Food Industry: Review), Moscow: VNIISUEINTIMedprom, 1990, issue 8.
Hawkins, E.G.E., Organic Peroxides. Their Formation and Reactions, London: F.F. Spon, 1961.
Emanuel’, N.M., Denisov, E.T., and Maizus, Z.K., Tsepnye reaktsii okisleniya uglevodorodov v zhidkoi faze (Chain Reactions of Liquid-Phase Oxidation of Hydrocarbons), Moscow: Nauka, 1965.
Nonhebel, D.C. and Walton, J.C., Free-Radical Chemistry. Structure and Mechanism, Cambridge: Univ., 1974.
Denisov, E.T. and Kovalev, G.I., Okislenie i stabilizatsiya reaktivnykh topliv (Oxidation and Stabilization of Jet Fuels), Moscow: Khimiya, 1983.
Denisov, E.T., Okislenie i destruktsiya karbotsepnykh polimerov (Oxidation and Degradation of Carbon-Chain Polymers), Leningrad: Khimiya, 1990.
Denisov, E.T., Konstanty skorosti gomoliticheskikh zhidkofaznykh reaktsii (Rate Constants of Homolytic Liquid-Phase Reactions), Moscow: Nauka, 1971.
Denisov, E.T., Mitskevich, V.E., and Agabekov, V.E., Mekhanizm zhidkofaznogo okisleniya kislorodsoderzhashchikh soedinenii (Mechanism of Liquid-Phase Oxidation of Oxygen-Containing Compounds), Minsk: Nauka i Tekhnika, 1975.
Roginskii, V.A., Fenol’nye antioksidanty: Reaktsionnaya sposobnost’ i effektivnost’ (Phenolic Antioxidants: Reactivity and Performance), Moscow: Nauka, 1988.
Golubeva, M.V., Ivanov, V.A., Potekhin, V.M., and Mikhailovskii, A.V., Zh. Prikl. Khim., 1987, vol. 60, no. 8, pp. 1841–1846.
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Original Russian Text © I.V. Zinchenko, V.A. Ivanov, V.M. Potekhin, 2006, published in Zhurnal Prikladnoi Khimii, 2006, Vol. 79, No. 6, pp. 986–991.
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Zinchenko, I.V., Ivanov, V.A. & Potekhin, V.M. Oxidation of soap chips and antioxidative stabilization with phenolic inhibitors. Russ J Appl Chem 79, 975–980 (2006). https://doi.org/10.1134/S107042720606019X
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DOI: https://doi.org/10.1134/S107042720606019X