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Loss of activity by vanadium sulfuric acid catalysts under the action of arsenic(III) oxide vapor

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Abstract

Chemical processes leading to inactivation of vanadium sulfuric acid catalysts by arsenic(III) oxide vapor were studied. The interaction and solubility in the system VO(H2AsO4)2-VOAsO4-H3AsO4-H2O and the composition of oxovanadium arsenate in a mixed oxidation state, used as a starting substance in synthesis of (VIVO)(VVO)2(As2O7)2, were examined.

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Authors and Affiliations

  1. Institute of Solid State Chemistry, Ural Division, Russian Academy of Sciences, Yekaterinburg, Russia

    V. N. Krasil’nikov, A. P. Shtin & V. I. Malkiman

  2. UNIKhIM SOZ Federal State Unitary Enterprise, Yekaterinburg, Russia

    V. N. Krasil’nikov, A. P. Shtin & V. I. Malkiman

Authors
  1. V. N. Krasil’nikov
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  2. A. P. Shtin
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  3. V. I. Malkiman
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Additional information

Original Russian Text © V. N. Krasil’nikov, A. P. Shtin, V. I. Malkiman, 2006, published in Zhurnal Prikladnoi Khimii, 2006, Vol. 79, No. 4, pp. 627–631.

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Krasil’nikov, V.N., Shtin, A.P. & Malkiman, V.I. Loss of activity by vanadium sulfuric acid catalysts under the action of arsenic(III) oxide vapor. Russ J Appl Chem 79, 619–623 (2006). https://doi.org/10.1134/S1070427206040227

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  • DOI: https://doi.org/10.1134/S1070427206040227

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