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Chemical Properties of 3a,6a-Diaza-1,4-diphosphapentalenes. Addition of p-Ditolyl Disulfide

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Abstract

Reaction of cyclohexane-annulated 3a,6a-diaza-1,4-diphosphapentalene with p-ditolyl disulfide gives the 1,4-adduct, while the double-decker ditriflate based on 2,3,5,6-tetramethyl-1H,4H-3a,6a-diaza-1,4-diphosphapentalene leads to the cross-deck adduct. The type of addition depends on the location of the HOMO: on the π-system of diazadiphosphapentalene in the first case, and in the interdeck space in the second.

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Funding

This work was financially supported by the Russian Science Foundation (grant no. 19-13-00400-П) using the equipment of the Center for Collective Use “Analytical Center of the IOMC RAS” with the financial support of the grant “Ensuring the development of the material and technical infrastructure of the centers for collective use of scientific equipment” (unique identifier RF-2296.61321X0017, agreement no. 075-15-2021-670).

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Authors and Affiliations

  1. G.A. Razuvaev Institute of Organometallic Chemistry of the Russian Academy of Sciences, 603137, Nizhny Novgorod, Russia

    V. V. Sushev, N. V. Zolotareva, M. D. Grishin, E. V. Baranov, G. K. Fukin & A. N. Kornev

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  1. V. V. Sushev
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  2. N. V. Zolotareva
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  3. M. D. Grishin
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  4. E. V. Baranov
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  5. G. K. Fukin
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  6. A. N. Kornev
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Correspondence to A. N. Kornev.

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To the 35th Anniversary of the founding of the G.A. Razuvaev Institute of Organometallic Chemistry of the Russian Academy of Sciences

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Sushev, V.V., Zolotareva, N.V., Grishin, M.D. et al. Chemical Properties of 3a,6a-Diaza-1,4-diphosphapentalenes. Addition of p-Ditolyl Disulfide. Russ J Gen Chem 93 (Suppl 3), S713–S721 (2023). https://doi.org/10.1134/S1070363223160089

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